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ZrO(2) coated Li(1.9)K(0.1)ZnTi(3)O(8) as an anode material for high-performance lithium-ion batteries

The Li(1.9)K(0.1)ZnTi(3)O(8)@ZrO(2) (1 wt%, 3 wt%, and 5 wt%) anode material was synthesized by doping Li(2)ZnTi(3)O(8) with potassium and coating ZrO(2), where the ZrO(2) coating layer was prepared by citric acid and zirconium acetate, and the potassium source was KCl. When the added ZrO(2) amount...

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Detalles Bibliográficos
Autores principales: Peng, Jing, Zeng, Xianguang, Zhu, Huafeng, Xia, Kui, Gong, Jing, Huang, Kaixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9627728/
https://www.ncbi.nlm.nih.gov/pubmed/36349001
http://dx.doi.org/10.1039/d2ra05555d
Descripción
Sumario:The Li(1.9)K(0.1)ZnTi(3)O(8)@ZrO(2) (1 wt%, 3 wt%, and 5 wt%) anode material was synthesized by doping Li(2)ZnTi(3)O(8) with potassium and coating ZrO(2), where the ZrO(2) coating layer was prepared by citric acid and zirconium acetate, and the potassium source was KCl. When the added ZrO(2) amount is 3%, the material has the most uniform size, reduced polarization, and reduced charge transfer resistance, and the specific capacity of LKZTO@ZrO(2) (3 w%) was 361.5 mA h g(−1) at 200 mA g(−1) at the 100th cycle, which is higher than that of LKZTO, of 311.3 mA h g(−1). The specific capacities of LKZTO@ZrO(2) (3 w%) at 50, 100, 200, 500, and 1000 mA g(−1) after 10 cycles were 424.9, 410.7, 394.1, 337.6 and 270.6 mA h g(−1), indicating that LKZTO@ZrO(2) (3 w%) has excellent electrochemical performance.