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ZrO(2) coated Li(1.9)K(0.1)ZnTi(3)O(8) as an anode material for high-performance lithium-ion batteries
The Li(1.9)K(0.1)ZnTi(3)O(8)@ZrO(2) (1 wt%, 3 wt%, and 5 wt%) anode material was synthesized by doping Li(2)ZnTi(3)O(8) with potassium and coating ZrO(2), where the ZrO(2) coating layer was prepared by citric acid and zirconium acetate, and the potassium source was KCl. When the added ZrO(2) amount...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9627728/ https://www.ncbi.nlm.nih.gov/pubmed/36349001 http://dx.doi.org/10.1039/d2ra05555d |
Sumario: | The Li(1.9)K(0.1)ZnTi(3)O(8)@ZrO(2) (1 wt%, 3 wt%, and 5 wt%) anode material was synthesized by doping Li(2)ZnTi(3)O(8) with potassium and coating ZrO(2), where the ZrO(2) coating layer was prepared by citric acid and zirconium acetate, and the potassium source was KCl. When the added ZrO(2) amount is 3%, the material has the most uniform size, reduced polarization, and reduced charge transfer resistance, and the specific capacity of LKZTO@ZrO(2) (3 w%) was 361.5 mA h g(−1) at 200 mA g(−1) at the 100th cycle, which is higher than that of LKZTO, of 311.3 mA h g(−1). The specific capacities of LKZTO@ZrO(2) (3 w%) at 50, 100, 200, 500, and 1000 mA g(−1) after 10 cycles were 424.9, 410.7, 394.1, 337.6 and 270.6 mA h g(−1), indicating that LKZTO@ZrO(2) (3 w%) has excellent electrochemical performance. |
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