Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2)

The reaction of elemental iodine and SO(3) in a sealed glass ampoule yielded a turquoise‐colored solution. At temperatures below 7 °C, deep red crystals of (I(4))[S(6)O(19)] grow. With the addition of B(2)O(3) and pyridine‐SO(3) complex red crystals of (I(4))[B(S(2)O(7))(2)](2) can be obtained after...

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Autores principales: van Gerven, David, Sutorius, Stefan, Bruns, Jörn, Wickleder, Mathias S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9630045/
https://www.ncbi.nlm.nih.gov/pubmed/35856862
http://dx.doi.org/10.1002/open.202200122
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author van Gerven, David
Sutorius, Stefan
Bruns, Jörn
Wickleder, Mathias S.
author_facet van Gerven, David
Sutorius, Stefan
Bruns, Jörn
Wickleder, Mathias S.
author_sort van Gerven, David
collection PubMed
description The reaction of elemental iodine and SO(3) in a sealed glass ampoule yielded a turquoise‐colored solution. At temperatures below 7 °C, deep red crystals of (I(4))[S(6)O(19)] grow. With the addition of B(2)O(3) and pyridine‐SO(3) complex red crystals of (I(4))[B(S(2)O(7))(2)](2) can be obtained after heating the mixture to 120 °C. The combination of an (I(4))(2+) cation with oxoanions has previously not been observed. Both anions have a significant but different influence on the structural properties of the (I(4))(2+) cation.
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spelling pubmed-96300452022-11-07 Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2) van Gerven, David Sutorius, Stefan Bruns, Jörn Wickleder, Mathias S. ChemistryOpen Research Articles The reaction of elemental iodine and SO(3) in a sealed glass ampoule yielded a turquoise‐colored solution. At temperatures below 7 °C, deep red crystals of (I(4))[S(6)O(19)] grow. With the addition of B(2)O(3) and pyridine‐SO(3) complex red crystals of (I(4))[B(S(2)O(7))(2)](2) can be obtained after heating the mixture to 120 °C. The combination of an (I(4))(2+) cation with oxoanions has previously not been observed. Both anions have a significant but different influence on the structural properties of the (I(4))(2+) cation. John Wiley and Sons Inc. 2022-07-20 /pmc/articles/PMC9630045/ /pubmed/35856862 http://dx.doi.org/10.1002/open.202200122 Text en © 2022 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Research Articles
van Gerven, David
Sutorius, Stefan
Bruns, Jörn
Wickleder, Mathias S.
Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2)
title Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2)
title_full Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2)
title_fullStr Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2)
title_full_unstemmed Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2)
title_short Stabilizing the Homopolycation (I(4))(2+) with a Hexasulfate in (I(4))[S(6)O(19)] and a Borosulfate in (I(4))[B(S(2)O(7))(2)](2)
title_sort stabilizing the homopolycation (i(4))(2+) with a hexasulfate in (i(4))[s(6)o(19)] and a borosulfate in (i(4))[b(s(2)o(7))(2)](2)
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9630045/
https://www.ncbi.nlm.nih.gov/pubmed/35856862
http://dx.doi.org/10.1002/open.202200122
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