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Crystal structure of ethyl 2-{4-[(2-oxo-3-phenyl-1,2-dihydroquinoxalin-1-yl)methyl]-1H-1,2,3-triazol-1-yl}acetate
The quinoxaline portion of the title molecule, C(21)H(19)N(5)O(3), is not quite planar as indicated by a dihedral angle of 3.38 (7)° between the constituent rings. The molecule is ‘U-shaped’, which is consolidated by an intramolecular antiparallel carbonyl electrostatic interaction with C··O di...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635411/ https://www.ncbi.nlm.nih.gov/pubmed/36341047 http://dx.doi.org/10.1107/S2414314622006939 |
Sumario: | The quinoxaline portion of the title molecule, C(21)H(19)N(5)O(3), is not quite planar as indicated by a dihedral angle of 3.38 (7)° between the constituent rings. The molecule is ‘U-shaped’, which is consolidated by an intramolecular antiparallel carbonyl electrostatic interaction with C··O distances of 2.8905 (16) and 3.0221 (15) Å, in the crystal forms corrugated layers through C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π(ring) and π-stacking interactions. [Image: see text] |
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