[(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate

The title compound, [Ir(C(8)H(12))(C(6)H(11)N(3))(C(18)H(33)P)]BF(4)·CH(2)Cl(2), a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetra­fluorido­borate counter-anion, crystallizes with one di­chloro­methane solvent mol­ecule per formula unit. The Ir(I) atom of the cationic...

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Detalles Bibliográficos
Autores principales: Rushlow, Joshua, Astashkin, Andrei V., Albert, Daniel R., Rajaseelan, Edward
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635413/
https://www.ncbi.nlm.nih.gov/pubmed/36341044
http://dx.doi.org/10.1107/S241431462200685X
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author Rushlow, Joshua
Astashkin, Andrei V.
Albert, Daniel R.
Rajaseelan, Edward
author_facet Rushlow, Joshua
Astashkin, Andrei V.
Albert, Daniel R.
Rajaseelan, Edward
author_sort Rushlow, Joshua
collection PubMed
description The title compound, [Ir(C(8)H(12))(C(6)H(11)N(3))(C(18)H(33)P)]BF(4)·CH(2)Cl(2), a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetra­fluorido­borate counter-anion, crystallizes with one di­chloro­methane solvent mol­ecule per formula unit. The Ir(I) atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tri­cyclo­hexyl­phosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units. [Image: see text]
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spelling pubmed-96354132022-11-04 [(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate Rushlow, Joshua Astashkin, Andrei V. Albert, Daniel R. Rajaseelan, Edward IUCrdata Data Reports The title compound, [Ir(C(8)H(12))(C(6)H(11)N(3))(C(18)H(33)P)]BF(4)·CH(2)Cl(2), a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetra­fluorido­borate counter-anion, crystallizes with one di­chloro­methane solvent mol­ecule per formula unit. The Ir(I) atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tri­cyclo­hexyl­phosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units. [Image: see text] International Union of Crystallography 2022-07-08 /pmc/articles/PMC9635413/ /pubmed/36341044 http://dx.doi.org/10.1107/S241431462200685X Text en © Rushlow et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Rushlow, Joshua
Astashkin, Andrei V.
Albert, Daniel R.
Rajaseelan, Edward
[(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate
title [(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate
title_full [(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate
title_fullStr [(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate
title_full_unstemmed [(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate
title_short [(1,2,5,6-η)-Cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κP)iridium(I) tetra­fluorido­borate di­chloro­methane monosolvate
title_sort [(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)(tri­cyclo­hexyl­phosphane-κp)iridium(i) tetra­fluorido­borate di­chloro­methane monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635413/
https://www.ncbi.nlm.nih.gov/pubmed/36341044
http://dx.doi.org/10.1107/S241431462200685X
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