Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)

The title compound, [Fe(2)Ga(2)(C(5)H(5))(2)Cl(4)(CO)(4)], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol­ecule has an inversion center located between the gallium atoms. The cycl...

Descripción completa

Detalles Bibliográficos
Autores principales: Harakas, George N., Demmin, Mary Elizabeth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635419/
https://www.ncbi.nlm.nih.gov/pubmed/36340981
http://dx.doi.org/10.1107/S241431462200832X
Descripción
Sumario:The title compound, [Fe(2)Ga(2)(C(5)H(5))(2)Cl(4)(CO)(4)], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol­ecule has an inversion center located between the gallium atoms. The cyclo­penta­dienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site. [Image: see text]

Ejemplares similares