Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)

The title compound, [Fe(2)Ga(2)(C(5)H(5))(2)Cl(4)(CO)(4)], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol­ecule has an inversion center located between the gallium atoms. The cycl...

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Detalles Bibliográficos
Autores principales: Harakas, George N., Demmin, Mary Elizabeth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635419/
https://www.ncbi.nlm.nih.gov/pubmed/36340981
http://dx.doi.org/10.1107/S241431462200832X
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author Harakas, George N.
Demmin, Mary Elizabeth
author_facet Harakas, George N.
Demmin, Mary Elizabeth
author_sort Harakas, George N.
collection PubMed
description The title compound, [Fe(2)Ga(2)(C(5)H(5))(2)Cl(4)(CO)(4)], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol­ecule has an inversion center located between the gallium atoms. The cyclo­penta­dienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site. [Image: see text]
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spelling pubmed-96354192022-11-04 Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga) Harakas, George N. Demmin, Mary Elizabeth IUCrdata Data Reports The title compound, [Fe(2)Ga(2)(C(5)H(5))(2)Cl(4)(CO)(4)], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol­ecule has an inversion center located between the gallium atoms. The cyclo­penta­dienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site. [Image: see text] International Union of Crystallography 2022-08-26 /pmc/articles/PMC9635419/ /pubmed/36340981 http://dx.doi.org/10.1107/S241431462200832X Text en © Harakas and Demmin 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Harakas, George N.
Demmin, Mary Elizabeth
Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)
title Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)
title_full Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)
title_fullStr Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)
title_full_unstemmed Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)
title_short Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)
title_sort tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η(5)-cyclo­penta­dien­yl)diirondigallium(2 fe—ga)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635419/
https://www.ncbi.nlm.nih.gov/pubmed/36340981
http://dx.doi.org/10.1107/S241431462200832X
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