Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate

The title cyclo­metalated distorted octa­hedral iridium complex, [Ir(C(11)H(6)F(2)N)(2)(C(12)H(12)N(2)O(2))]PF(6), exhibits elongated Ir—N bonds to the dimeth­oxy bi­pyridine ligand [2.128 (3) and 2.136 (3) Å] where these nitro­gen atoms are trans to the Ir—C bonds of the two cyclo­metalating di­flu...

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Detalles Bibliográficos
Autores principales: Shevlin, Madelyn R., Stumbo, Emily E., McMillen, Colin D., Pienkos, Jared A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635420/
https://www.ncbi.nlm.nih.gov/pubmed/36340976
http://dx.doi.org/10.1107/S2414314622008306
Descripción
Sumario:The title cyclo­metalated distorted octa­hedral iridium complex, [Ir(C(11)H(6)F(2)N)(2)(C(12)H(12)N(2)O(2))]PF(6), exhibits elongated Ir—N bonds to the dimeth­oxy bi­pyridine ligand [2.128 (3) and 2.136 (3) Å] where these nitro­gen atoms are trans to the Ir—C bonds of the two cyclo­metalating di­fluoro­phenyl­pyridine ligands. The angles between the mean planes of the phenyl and pyridyl fragments within the individual ligands range from 3.5 (2) to 11.4 (2)° to deviate slightly from coplanarity. [Image: see text]

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