Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate

The title cyclo­metalated distorted octa­hedral iridium complex, [Ir(C(11)H(6)F(2)N)(2)(C(12)H(12)N(2)O(2))]PF(6), exhibits elongated Ir—N bonds to the dimeth­oxy bi­pyridine ligand [2.128 (3) and 2.136 (3) Å] where these nitro­gen atoms are trans to the Ir—C bonds of the two cyclo­metalating di­flu...

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Autores principales: Shevlin, Madelyn R., Stumbo, Emily E., McMillen, Colin D., Pienkos, Jared A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635420/
https://www.ncbi.nlm.nih.gov/pubmed/36340976
http://dx.doi.org/10.1107/S2414314622008306
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author Shevlin, Madelyn R.
Stumbo, Emily E.
McMillen, Colin D.
Pienkos, Jared A.
author_facet Shevlin, Madelyn R.
Stumbo, Emily E.
McMillen, Colin D.
Pienkos, Jared A.
author_sort Shevlin, Madelyn R.
collection PubMed
description The title cyclo­metalated distorted octa­hedral iridium complex, [Ir(C(11)H(6)F(2)N)(2)(C(12)H(12)N(2)O(2))]PF(6), exhibits elongated Ir—N bonds to the dimeth­oxy bi­pyridine ligand [2.128 (3) and 2.136 (3) Å] where these nitro­gen atoms are trans to the Ir—C bonds of the two cyclo­metalating di­fluoro­phenyl­pyridine ligands. The angles between the mean planes of the phenyl and pyridyl fragments within the individual ligands range from 3.5 (2) to 11.4 (2)° to deviate slightly from coplanarity. [Image: see text]
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spelling pubmed-96354202022-11-04 Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate Shevlin, Madelyn R. Stumbo, Emily E. McMillen, Colin D. Pienkos, Jared A. IUCrdata Data Reports The title cyclo­metalated distorted octa­hedral iridium complex, [Ir(C(11)H(6)F(2)N)(2)(C(12)H(12)N(2)O(2))]PF(6), exhibits elongated Ir—N bonds to the dimeth­oxy bi­pyridine ligand [2.128 (3) and 2.136 (3) Å] where these nitro­gen atoms are trans to the Ir—C bonds of the two cyclo­metalating di­fluoro­phenyl­pyridine ligands. The angles between the mean planes of the phenyl and pyridyl fragments within the individual ligands range from 3.5 (2) to 11.4 (2)° to deviate slightly from coplanarity. [Image: see text] International Union of Crystallography 2022-08-26 /pmc/articles/PMC9635420/ /pubmed/36340976 http://dx.doi.org/10.1107/S2414314622008306 Text en © Shevlin et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shevlin, Madelyn R.
Stumbo, Emily E.
McMillen, Colin D.
Pienkos, Jared A.
Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate
title Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate
title_full Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate
title_fullStr Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate
title_full_unstemmed Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate
title_short Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate
title_sort bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(iii) hexa­fluorido­phosphate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635420/
https://www.ncbi.nlm.nih.gov/pubmed/36340976
http://dx.doi.org/10.1107/S2414314622008306
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AT mcmillencolind bis35difluoro2pyridin2ylphenyl44dimethoxy22bipyridineiridiumiiihexafluoridophosphate
AT pienkosjareda bis35difluoro2pyridin2ylphenyl44dimethoxy22bipyridineiridiumiiihexafluoridophosphate

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