catena-Poly[[(benzyl­diphenyl­phosphine-κP)silver(I)]-μ-nitrato-κ(2) O:O′-[(benzyl­diphenyl­phosphine-κP)silver(I)]-μ-nitrato-κ(4) O,O′:O′,O′′]

The structure of the title complex, [Ag(2)(NO(3))(2)(C(19)H(17)P)(2)]( n ), reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of a...

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Detalles Bibliográficos
Autores principales: Potgieter, Kariska, Malan, Frederick P., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635421/
https://www.ncbi.nlm.nih.gov/pubmed/36340977
http://dx.doi.org/10.1107/S2414314622007726
Descripción
Sumario:The structure of the title complex, [Ag(2)(NO(3))(2)(C(19)H(17)P)(2)]( n ), reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetra­hedral shape. [Image: see text]

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