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catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2) O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4) O,O′:O′,O′′]
The structure of the title complex, [Ag(2)(NO(3))(2)(C(19)H(17)P)(2)]( n ), reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635421/ https://www.ncbi.nlm.nih.gov/pubmed/36340977 http://dx.doi.org/10.1107/S2414314622007726 |
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author | Potgieter, Kariska Malan, Frederick P. Meijboom, Reinout |
author_facet | Potgieter, Kariska Malan, Frederick P. Meijboom, Reinout |
author_sort | Potgieter, Kariska |
collection | PubMed |
description | The structure of the title complex, [Ag(2)(NO(3))(2)(C(19)H(17)P)(2)]( n ), reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetrahedral shape. [Image: see text] |
format | Online Article Text |
id | pubmed-9635421 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-96354212022-11-04 catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2) O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4) O,O′:O′,O′′] Potgieter, Kariska Malan, Frederick P. Meijboom, Reinout IUCrdata Data Reports The structure of the title complex, [Ag(2)(NO(3))(2)(C(19)H(17)P)(2)]( n ), reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetrahedral shape. [Image: see text] International Union of Crystallography 2022-08-12 /pmc/articles/PMC9635421/ /pubmed/36340977 http://dx.doi.org/10.1107/S2414314622007726 Text en © Potgieter et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Potgieter, Kariska Malan, Frederick P. Meijboom, Reinout catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2) O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4) O,O′:O′,O′′] |
title |
catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2)
O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4)
O,O′:O′,O′′] |
title_full |
catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2)
O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4)
O,O′:O′,O′′] |
title_fullStr |
catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2)
O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4)
O,O′:O′,O′′] |
title_full_unstemmed |
catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2)
O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4)
O,O′:O′,O′′] |
title_short |
catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(2)
O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ(4)
O,O′:O′,O′′] |
title_sort | catena-poly[[(benzyldiphenylphosphine-κp)silver(i)]-μ-nitrato-κ(2)
o:o′-[(benzyldiphenylphosphine-κp)silver(i)]-μ-nitrato-κ(4)
o,o′:o′,o′′] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635421/ https://www.ncbi.nlm.nih.gov/pubmed/36340977 http://dx.doi.org/10.1107/S2414314622007726 |
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