Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)

The title Ag(I) complex, [Ag(NO(2))(C(19)H(17)P)(2)], reveals a distorted pseudo-trigonal–planar shape around the Ag(I) atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this descri...

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Detalles Bibliográficos
Autores principales: Potgieter, Kariska, Malan, Frederick P., Alimi, Oyekunle Azeez, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635422/
https://www.ncbi.nlm.nih.gov/pubmed/36340974
http://dx.doi.org/10.1107/S2414314622007714
Descripción
Sumario:The title Ag(I) complex, [Ag(NO(2))(C(19)H(17)P)(2)], reveals a distorted pseudo-trigonal–planar shape around the Ag(I) atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O—Ag—O angle of 51.44 (9)°. The plane resulting from the NO(2) coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°]. [Image: see text]

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