Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)

The title Ag(I) complex, [Ag(NO(2))(C(19)H(17)P)(2)], reveals a distorted pseudo-trigonal–planar shape around the Ag(I) atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this descri...

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Detalles Bibliográficos
Autores principales: Potgieter, Kariska, Malan, Frederick P., Alimi, Oyekunle Azeez, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635422/
https://www.ncbi.nlm.nih.gov/pubmed/36340974
http://dx.doi.org/10.1107/S2414314622007714
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author Potgieter, Kariska
Malan, Frederick P.
Alimi, Oyekunle Azeez
Meijboom, Reinout
author_facet Potgieter, Kariska
Malan, Frederick P.
Alimi, Oyekunle Azeez
Meijboom, Reinout
author_sort Potgieter, Kariska
collection PubMed
description The title Ag(I) complex, [Ag(NO(2))(C(19)H(17)P)(2)], reveals a distorted pseudo-trigonal–planar shape around the Ag(I) atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O—Ag—O angle of 51.44 (9)°. The plane resulting from the NO(2) coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°]. [Image: see text]
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spelling pubmed-96354222022-11-04 Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I) Potgieter, Kariska Malan, Frederick P. Alimi, Oyekunle Azeez Meijboom, Reinout IUCrdata Data Reports The title Ag(I) complex, [Ag(NO(2))(C(19)H(17)P)(2)], reveals a distorted pseudo-trigonal–planar shape around the Ag(I) atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O—Ag—O angle of 51.44 (9)°. The plane resulting from the NO(2) coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°]. [Image: see text] International Union of Crystallography 2022-08-12 /pmc/articles/PMC9635422/ /pubmed/36340974 http://dx.doi.org/10.1107/S2414314622007714 Text en © Potgieter et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Potgieter, Kariska
Malan, Frederick P.
Alimi, Oyekunle Azeez
Meijboom, Reinout
Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)
title Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)
title_full Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)
title_fullStr Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)
title_full_unstemmed Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)
title_short Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ(2) O,O′)silver(I)
title_sort bis[(4-methyl­phen­yl)di­phenyl­phosphine-κp](nitrito-κ(2) o,o′)silver(i)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635422/
https://www.ncbi.nlm.nih.gov/pubmed/36340974
http://dx.doi.org/10.1107/S2414314622007714
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