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Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate
The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hydroxyphenyl N-{4-[(4-hydroxyphenoxycarbonyl)amino]phenyl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The molecule is centrosymmetric, and displays a twisted conformation for t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635426/ https://www.ncbi.nlm.nih.gov/pubmed/36337456 http://dx.doi.org/10.1107/S2414314622009191 |
Sumario: | The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hydroxyphenyl N-{4-[(4-hydroxyphenoxycarbonyl)amino]phenyl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The molecule is centrosymmetric, and displays a twisted conformation for the three aromatic rings [the dihedral angle between central benzene ring and the urethane group is 33.4 (6)°, and that between the latter and the terminal ring is 65.1 (1)°]. In the crystal, a three-dimensional framework is formed through O—H⋯O and N—H⋯O hydrogen bonds involving the hydroxy and urethane functional groups, respectively. [Image: see text] |
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