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Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate

The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hy­droxy­phenyl N-{4-[(4-hy­droxy­phen­oxy­carbon­yl)amino]­phen­yl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The mol­ecule is centrosymmetric, and displays a twisted conformation for t...

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Detalles Bibliográficos
Autores principales: Martínez-de la Luz, Isabel, López-Velázquez, Delia, Bernès, Sylvain, Varela Caselis, Jenaro L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635426/
https://www.ncbi.nlm.nih.gov/pubmed/36337456
http://dx.doi.org/10.1107/S2414314622009191
Descripción
Sumario:The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hy­droxy­phenyl N-{4-[(4-hy­droxy­phen­oxy­carbon­yl)amino]­phen­yl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The mol­ecule is centrosymmetric, and displays a twisted conformation for the three aromatic rings [the dihedral angle between central benzene ring and the urethane group is 33.4 (6)°, and that between the latter and the terminal ring is 65.1 (1)°]. In the crystal, a three-dimensional framework is formed through O—H⋯O and N—H⋯O hydrogen bonds involving the hy­droxy and urethane functional groups, respectively. [Image: see text]