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Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate
The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hydroxyphenyl N-{4-[(4-hydroxyphenoxycarbonyl)amino]phenyl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The molecule is centrosymmetric, and displays a twisted conformation for t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635426/ https://www.ncbi.nlm.nih.gov/pubmed/36337456 http://dx.doi.org/10.1107/S2414314622009191 |
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author | Martínez-de la Luz, Isabel López-Velázquez, Delia Bernès, Sylvain Varela Caselis, Jenaro L. |
author_facet | Martínez-de la Luz, Isabel López-Velázquez, Delia Bernès, Sylvain Varela Caselis, Jenaro L. |
author_sort | Martínez-de la Luz, Isabel |
collection | PubMed |
description | The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hydroxyphenyl N-{4-[(4-hydroxyphenoxycarbonyl)amino]phenyl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The molecule is centrosymmetric, and displays a twisted conformation for the three aromatic rings [the dihedral angle between central benzene ring and the urethane group is 33.4 (6)°, and that between the latter and the terminal ring is 65.1 (1)°]. In the crystal, a three-dimensional framework is formed through O—H⋯O and N—H⋯O hydrogen bonds involving the hydroxy and urethane functional groups, respectively. [Image: see text] |
format | Online Article Text |
id | pubmed-9635426 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-96354262022-11-04 Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate Martínez-de la Luz, Isabel López-Velázquez, Delia Bernès, Sylvain Varela Caselis, Jenaro L. IUCrdata Data Reports The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hydroxyphenyl N-{4-[(4-hydroxyphenoxycarbonyl)amino]phenyl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The molecule is centrosymmetric, and displays a twisted conformation for the three aromatic rings [the dihedral angle between central benzene ring and the urethane group is 33.4 (6)°, and that between the latter and the terminal ring is 65.1 (1)°]. In the crystal, a three-dimensional framework is formed through O—H⋯O and N—H⋯O hydrogen bonds involving the hydroxy and urethane functional groups, respectively. [Image: see text] International Union of Crystallography 2022-09-27 /pmc/articles/PMC9635426/ /pubmed/36337456 http://dx.doi.org/10.1107/S2414314622009191 Text en © Martínez-de la Luz et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Martínez-de la Luz, Isabel López-Velázquez, Delia Bernès, Sylvain Varela Caselis, Jenaro L. Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate |
title | Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate |
title_full | Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate |
title_fullStr | Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate |
title_full_unstemmed | Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate |
title_short | Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate |
title_sort | bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635426/ https://www.ncbi.nlm.nih.gov/pubmed/36337456 http://dx.doi.org/10.1107/S2414314622009191 |
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