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Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate

The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hy­droxy­phenyl N-{4-[(4-hy­droxy­phen­oxy­carbon­yl)amino]­phen­yl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The mol­ecule is centrosymmetric, and displays a twisted conformation for t...

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Detalles Bibliográficos
Autores principales: Martínez-de la Luz, Isabel, López-Velázquez, Delia, Bernès, Sylvain, Varela Caselis, Jenaro L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635426/
https://www.ncbi.nlm.nih.gov/pubmed/36337456
http://dx.doi.org/10.1107/S2414314622009191
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author Martínez-de la Luz, Isabel
López-Velázquez, Delia
Bernès, Sylvain
Varela Caselis, Jenaro L.
author_facet Martínez-de la Luz, Isabel
López-Velázquez, Delia
Bernès, Sylvain
Varela Caselis, Jenaro L.
author_sort Martínez-de la Luz, Isabel
collection PubMed
description The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hy­droxy­phenyl N-{4-[(4-hy­droxy­phen­oxy­carbon­yl)amino]­phen­yl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The mol­ecule is centrosymmetric, and displays a twisted conformation for the three aromatic rings [the dihedral angle between central benzene ring and the urethane group is 33.4 (6)°, and that between the latter and the terminal ring is 65.1 (1)°]. In the crystal, a three-dimensional framework is formed through O—H⋯O and N—H⋯O hydrogen bonds involving the hy­droxy and urethane functional groups, respectively. [Image: see text]
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spelling pubmed-96354262022-11-04 Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate Martínez-de la Luz, Isabel López-Velázquez, Delia Bernès, Sylvain Varela Caselis, Jenaro L. IUCrdata Data Reports The title compound, C(20)H(16)N(2)O(6) (systematic name: 4-hy­droxy­phenyl N-{4-[(4-hy­droxy­phen­oxy­carbon­yl)amino]­phen­yl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The mol­ecule is centrosymmetric, and displays a twisted conformation for the three aromatic rings [the dihedral angle between central benzene ring and the urethane group is 33.4 (6)°, and that between the latter and the terminal ring is 65.1 (1)°]. In the crystal, a three-dimensional framework is formed through O—H⋯O and N—H⋯O hydrogen bonds involving the hy­droxy and urethane functional groups, respectively. [Image: see text] International Union of Crystallography 2022-09-27 /pmc/articles/PMC9635426/ /pubmed/36337456 http://dx.doi.org/10.1107/S2414314622009191 Text en © Martínez-de la Luz et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Martínez-de la Luz, Isabel
López-Velázquez, Delia
Bernès, Sylvain
Varela Caselis, Jenaro L.
Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate
title Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate
title_full Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate
title_fullStr Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate
title_full_unstemmed Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate
title_short Bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate
title_sort bis(4-hy­droxy­phen­yl) 1,4-phenyl­enebiscarbamate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635426/
https://www.ncbi.nlm.nih.gov/pubmed/36337456
http://dx.doi.org/10.1107/S2414314622009191
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