2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)

The title compound, C(20)H(14)I(2)N(2)O(2), a di­iodo-Schiff base, crystallizes in space group Pbca with one mol­ecule per asymmetric unit. The mol­ecular structure reveals two intra­molecular O—H⋯N hydrogen bonds that give the mol­ecule a twisted structure with non-coplanar rings. In the crystal st...

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Autores principales: Blackwelder, Lauren A., Kelley, Andrea R., Balaich, Gary J., Jefferies, Latisha R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635427/
https://www.ncbi.nlm.nih.gov/pubmed/36337458
http://dx.doi.org/10.1107/S2414314622008951
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author Blackwelder, Lauren A.
Kelley, Andrea R.
Balaich, Gary J.
Jefferies, Latisha R.
author_facet Blackwelder, Lauren A.
Kelley, Andrea R.
Balaich, Gary J.
Jefferies, Latisha R.
author_sort Blackwelder, Lauren A.
collection PubMed
description The title compound, C(20)H(14)I(2)N(2)O(2), a di­iodo-Schiff base, crystallizes in space group Pbca with one mol­ecule per asymmetric unit. The mol­ecular structure reveals two intra­molecular O—H⋯N hydrogen bonds that give the mol­ecule a twisted structure with non-coplanar rings. In the crystal structure, the mol­ecular packing is stabilized by π–π stacking, hydrogen- and halogen-bonding (C—H⋯I; O⋯I) inter­actions. [Image: see text]
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spelling pubmed-96354272022-11-04 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol) Blackwelder, Lauren A. Kelley, Andrea R. Balaich, Gary J. Jefferies, Latisha R. IUCrdata Data Reports The title compound, C(20)H(14)I(2)N(2)O(2), a di­iodo-Schiff base, crystallizes in space group Pbca with one mol­ecule per asymmetric unit. The mol­ecular structure reveals two intra­molecular O—H⋯N hydrogen bonds that give the mol­ecule a twisted structure with non-coplanar rings. In the crystal structure, the mol­ecular packing is stabilized by π–π stacking, hydrogen- and halogen-bonding (C—H⋯I; O⋯I) inter­actions. [Image: see text] International Union of Crystallography 2022-09-13 /pmc/articles/PMC9635427/ /pubmed/36337458 http://dx.doi.org/10.1107/S2414314622008951 Text en © Blackwelder et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Blackwelder, Lauren A.
Kelley, Andrea R.
Balaich, Gary J.
Jefferies, Latisha R.
2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)
title 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)
title_full 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)
title_fullStr 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)
title_full_unstemmed 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)
title_short 2,2′-{(1E,1′E)-[Ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)
title_sort 2,2′-{(1e,1′e)-[ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(4-iodo­phenol)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635427/
https://www.ncbi.nlm.nih.gov/pubmed/36337458
http://dx.doi.org/10.1107/S2414314622008951
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