μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)]

In the crystal structure of the title oxido-bridged binuclear complex, [Mn(III)(TPP)](2)O (TPP = tetra­phenyl­porphyrinate, C(44)H(28)N(4)) or [Mn(2)(C(44)H(28)N(4))(2)O], the two penta­coordinate manganese(III) ions are bridged by a single oxido ligand, with an Mn—O distance of 1.7600 (3) Å and an...

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Detalles Bibliográficos
Autores principales: Ren, Wanjie, Li, Jianfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635429/
https://www.ncbi.nlm.nih.gov/pubmed/36337454
http://dx.doi.org/10.1107/S2414314622008690
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author Ren, Wanjie
Li, Jianfeng
author_facet Ren, Wanjie
Li, Jianfeng
author_sort Ren, Wanjie
collection PubMed
description In the crystal structure of the title oxido-bridged binuclear complex, [Mn(III)(TPP)](2)O (TPP = tetra­phenyl­porphyrinate, C(44)H(28)N(4)) or [Mn(2)(C(44)H(28)N(4))(2)O], the two penta­coordinate manganese(III) ions are bridged by a single oxido ligand, with an Mn—O distance of 1.7600 (3) Å and an Mn—O—Mn bridging angle of 176.1 (2)°. The bridging O(2−) ligand is located on a twofold rotation axis, resulting in point group 2 for the entire complex. The Mn(III) atom is displaced out of the 24-atom mean plane of the porphyrine entity by 0.52 Å. C—H⋯π and π–π inter­actions help to stabilize the mol­ecular packing within the crystal structure. [Image: see text]
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spelling pubmed-96354292022-11-04 μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)] Ren, Wanjie Li, Jianfeng IUCrdata Data Reports In the crystal structure of the title oxido-bridged binuclear complex, [Mn(III)(TPP)](2)O (TPP = tetra­phenyl­porphyrinate, C(44)H(28)N(4)) or [Mn(2)(C(44)H(28)N(4))(2)O], the two penta­coordinate manganese(III) ions are bridged by a single oxido ligand, with an Mn—O distance of 1.7600 (3) Å and an Mn—O—Mn bridging angle of 176.1 (2)°. The bridging O(2−) ligand is located on a twofold rotation axis, resulting in point group 2 for the entire complex. The Mn(III) atom is displaced out of the 24-atom mean plane of the porphyrine entity by 0.52 Å. C—H⋯π and π–π inter­actions help to stabilize the mol­ecular packing within the crystal structure. [Image: see text] International Union of Crystallography 2022-09-02 /pmc/articles/PMC9635429/ /pubmed/36337454 http://dx.doi.org/10.1107/S2414314622008690 Text en © Ren and Li 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ren, Wanjie
Li, Jianfeng
μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)]
title μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)]
title_full μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)]
title_fullStr μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)]
title_full_unstemmed μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)]
title_short μ-Oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)manganese(III)]
title_sort μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n,n′,n′′,n′′′)manganese(iii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635429/
https://www.ncbi.nlm.nih.gov/pubmed/36337454
http://dx.doi.org/10.1107/S2414314622008690
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AT lijianfeng moxidobis5101520tetraphenylporphyrinatok4nnnnmanganeseiii

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