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Deconvolution of metal apportionment in bulk metal-organic frameworks

We report a general route to decipher the apportionment of metal ions in bulk metal-organic frameworks (MOFs) by solid-state nuclear magnetic resonance spectroscopy. We demonstrate this route in Mg(1−x)Ni(x)-MOF-74, where we uncover all eight possible atomic-scale Mg/Ni arrangements through identifi...

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Detalles Bibliográficos
Autores principales: Xu, Jun, Liu, Xingwu, Liu, Xingchen, Yan, Tao, Wan, Hongliu, Cao, Zhi, Reimer, Jeffrey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635837/
https://www.ncbi.nlm.nih.gov/pubmed/36332019
http://dx.doi.org/10.1126/sciadv.add5503

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