Ethidium tetra­phenyl­borate aceto­nitrile disolvate

In the title solvated salt, (C(21)H(20)N(3)){B(C(6)H(5))(4)}·2CH(3)CN (systematic name 3,8-di­amino-5-ethyl-6-phenyl­phenanthridin-5-ium tetra­phenyl­borate aceto­nitrile disolvate), the dihedral angle between the tricyclic fused ring system (r.m.s. deviation = 0.021 Å) and the pendant phenyl group...

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Detalles Bibliográficos
Autores principales: Shimazaki, Runa, Sadakiyo, Masaaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638059/
https://www.ncbi.nlm.nih.gov/pubmed/36405848
http://dx.doi.org/10.1107/S2414314622009518
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author Shimazaki, Runa
Sadakiyo, Masaaki
author_facet Shimazaki, Runa
Sadakiyo, Masaaki
author_sort Shimazaki, Runa
collection PubMed
description In the title solvated salt, (C(21)H(20)N(3)){B(C(6)H(5))(4)}·2CH(3)CN (systematic name 3,8-di­amino-5-ethyl-6-phenyl­phenanthridin-5-ium tetra­phenyl­borate aceto­nitrile disolvate), the dihedral angle between the tricyclic fused ring system (r.m.s. deviation = 0.021 Å) and the pendant phenyl group of the ethidium cation is 84.91 (7)°. The {B(C(6)H(5))(4)}(−) anion has a typical tetra­hedral structure. The aceto­nitrile solvent mol­ecules do not accept hydrogen bonds from the –NH(2) groups of the ethidium ions. [Image: see text]
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spelling pubmed-96380592022-11-18 Ethidium tetra­phenyl­borate aceto­nitrile disolvate Shimazaki, Runa Sadakiyo, Masaaki IUCrdata Data Reports In the title solvated salt, (C(21)H(20)N(3)){B(C(6)H(5))(4)}·2CH(3)CN (systematic name 3,8-di­amino-5-ethyl-6-phenyl­phenanthridin-5-ium tetra­phenyl­borate aceto­nitrile disolvate), the dihedral angle between the tricyclic fused ring system (r.m.s. deviation = 0.021 Å) and the pendant phenyl group of the ethidium cation is 84.91 (7)°. The {B(C(6)H(5))(4)}(−) anion has a typical tetra­hedral structure. The aceto­nitrile solvent mol­ecules do not accept hydrogen bonds from the –NH(2) groups of the ethidium ions. [Image: see text] International Union of Crystallography 2022-10-11 /pmc/articles/PMC9638059/ /pubmed/36405848 http://dx.doi.org/10.1107/S2414314622009518 Text en © Shimazaki and Sadakiyo 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shimazaki, Runa
Sadakiyo, Masaaki
Ethidium tetra­phenyl­borate aceto­nitrile disolvate
title Ethidium tetra­phenyl­borate aceto­nitrile disolvate
title_full Ethidium tetra­phenyl­borate aceto­nitrile disolvate
title_fullStr Ethidium tetra­phenyl­borate aceto­nitrile disolvate
title_full_unstemmed Ethidium tetra­phenyl­borate aceto­nitrile disolvate
title_short Ethidium tetra­phenyl­borate aceto­nitrile disolvate
title_sort ethidium tetra­phenyl­borate aceto­nitrile disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638059/
https://www.ncbi.nlm.nih.gov/pubmed/36405848
http://dx.doi.org/10.1107/S2414314622009518
work_keys_str_mv AT shimazakiruna ethidiumtetraphenylborateacetonitriledisolvate
AT sadakiyomasaaki ethidiumtetraphenylborateacetonitriledisolvate

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