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Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties

Hydrosilylation epoxidized eugenol (HSI-EP-EU) is successfully synthesized and used as a reactive diluent for epoxy/anhydride (marked as P) and epoxy/imidazole (marked as I) curing systems. The reactive bio-based diluent HSI-EP-EU has an excellent dilution effect on petroleum-based epoxy resin (E44)...

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Detalles Bibliográficos
Autores principales: Li, Jingyu, Zhao, Haichao, Sui, Guoxin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638842/
https://www.ncbi.nlm.nih.gov/pubmed/36380949
http://dx.doi.org/10.1039/d2ra05160e
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author Li, Jingyu
Zhao, Haichao
Sui, Guoxin
author_facet Li, Jingyu
Zhao, Haichao
Sui, Guoxin
author_sort Li, Jingyu
collection PubMed
description Hydrosilylation epoxidized eugenol (HSI-EP-EU) is successfully synthesized and used as a reactive diluent for epoxy/anhydride (marked as P) and epoxy/imidazole (marked as I) curing systems. The reactive bio-based diluent HSI-EP-EU has an excellent dilution effect on petroleum-based epoxy resin (E44). The curing kinetics of P + HSI-EP-EU and I + HSI-EP-EU are studied by a non-isothermal DSC method. The kinetics parameters are calculated by using the Kissinger model, Crnae model, Ozawa model and β-T (temperature-heating speed) extrapolation, respectively, to determine theoretically reasonable curing conditions. In addition, the effects of HSI-EP-EU on the antibacterial properties, thermo-mechanical properties and thermal stability of P + HSI-EP-EU and I + HSI-EP-EU systems are also studied. It is found that HSI-EP-EU possessed obvious antibacterial properties and could effectively improve the mechanical properties for the I + HSI-EP-EU.
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spelling pubmed-96388422022-11-14 Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties Li, Jingyu Zhao, Haichao Sui, Guoxin RSC Adv Chemistry Hydrosilylation epoxidized eugenol (HSI-EP-EU) is successfully synthesized and used as a reactive diluent for epoxy/anhydride (marked as P) and epoxy/imidazole (marked as I) curing systems. The reactive bio-based diluent HSI-EP-EU has an excellent dilution effect on petroleum-based epoxy resin (E44). The curing kinetics of P + HSI-EP-EU and I + HSI-EP-EU are studied by a non-isothermal DSC method. The kinetics parameters are calculated by using the Kissinger model, Crnae model, Ozawa model and β-T (temperature-heating speed) extrapolation, respectively, to determine theoretically reasonable curing conditions. In addition, the effects of HSI-EP-EU on the antibacterial properties, thermo-mechanical properties and thermal stability of P + HSI-EP-EU and I + HSI-EP-EU systems are also studied. It is found that HSI-EP-EU possessed obvious antibacterial properties and could effectively improve the mechanical properties for the I + HSI-EP-EU. The Royal Society of Chemistry 2022-11-07 /pmc/articles/PMC9638842/ /pubmed/36380949 http://dx.doi.org/10.1039/d2ra05160e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Li, Jingyu
Zhao, Haichao
Sui, Guoxin
Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
title Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
title_full Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
title_fullStr Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
title_full_unstemmed Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
title_short Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
title_sort renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638842/
https://www.ncbi.nlm.nih.gov/pubmed/36380949
http://dx.doi.org/10.1039/d2ra05160e
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AT zhaohaichao renewablegreenreactivediluentforbisphenolaepoxyresinsystemcuringkineticsandproperties
AT suiguoxin renewablegreenreactivediluentforbisphenolaepoxyresinsystemcuringkineticsandproperties