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Gold nanoparticle decorated dithiocarbamate modified natural boehmite as a catalyst for the synthesis of biologically essential propargylamines

Here, we prepare an Au NP decorated dithiocarbamate functionalized boehmite (γ-AlO(OH)@C-NHCS(2)H·Au(NPs)). This stepwise synthetic method gives an efficient, cost-effective, and green heterogenous Au-based nanocatalyst for the A(3)-coupling preparation of the biologically essential propargylamines....

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Detalles Bibliográficos
Autores principales: Zarenezhad, Elham, Taghavi, Reza, Kamrani, Parisa, Farjam, Mojtaba, Rostamnia, Sadegh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638948/
https://www.ncbi.nlm.nih.gov/pubmed/36380962
http://dx.doi.org/10.1039/d2ra03725d
Descripción
Sumario:Here, we prepare an Au NP decorated dithiocarbamate functionalized boehmite (γ-AlO(OH)@C-NHCS(2)H·Au(NPs)). This stepwise synthetic method gives an efficient, cost-effective, and green heterogenous Au-based nanocatalyst for the A(3)-coupling preparation of the biologically essential propargylamines. Different characterization methods, including FT-IR, XRD, SEM, TEM, EDX spectra, and elemental SEM-mapping, were employed to investigate the structure of the manufactured γ-AlO(OH)@C-NHCS(2)H·Au(NPs). Then we used the prepared composite as a heterogeneous gold-based nanocatalyst for the one-pot A(3)-coupling preparation of propargyl amines by reacting a variety of aldehydes, amines, and phenylacetylene which exhibited promising results.