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Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′]

The title polymer, [Cu(SO(4))(CH(5)N(3)O)(2)]( n ), has been synthesized from aqueous solutions of CuSO(4) and semicarbazide. In the crystal structure, the Cu(II) atoms are chelated by two neutral semicarbazide mol­ecules through the oxygen atom and a nitro­gen atom of the amino group. The remaining...

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Autores principales: Tadjieva, Galiya, Ibragimov, Aziz B., Yakubov, Yuldash, Ibragimov, Bakhtiyar T., Ashurov, Jamshid M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638975/
https://www.ncbi.nlm.nih.gov/pubmed/36380913
http://dx.doi.org/10.1107/S2056989022010040
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author Tadjieva, Galiya
Ibragimov, Aziz B.
Yakubov, Yuldash
Ibragimov, Bakhtiyar T.
Ashurov, Jamshid M.
author_facet Tadjieva, Galiya
Ibragimov, Aziz B.
Yakubov, Yuldash
Ibragimov, Bakhtiyar T.
Ashurov, Jamshid M.
author_sort Tadjieva, Galiya
collection PubMed
description The title polymer, [Cu(SO(4))(CH(5)N(3)O)(2)]( n ), has been synthesized from aqueous solutions of CuSO(4) and semicarbazide. In the crystal structure, the Cu(II) atoms are chelated by two neutral semicarbazide mol­ecules through the oxygen atom and a nitro­gen atom of the amino group. The remaining two positions of the Jahn–Teller-distorted octa­hedral coordination sphere are occupied by oxygen atoms of two sulfate anions in the axial positions. The coordination bonds of the latter associate the polyhedra into polymeric chains running parallel to the c axis. There is a weak intra­molecular hydrogen bond between the N—H group and an oxygen atom of the SO(4) (2–) anion. Thirteen relatively weak inter­molecular hydrogen-bonding inter­actions link the chains into a three-dimensional network. Hirshfeld surface analysis revealed that 64.7% of the inter­molecular inter­actions are from O⋯H/H⋯O contacts and 20.1% from H⋯H contacts. Other inter­actions such as N⋯H/H⋯N or C⋯H/H⋯C contribute less to the crystal packing.
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spelling pubmed-96389752022-11-14 Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′] Tadjieva, Galiya Ibragimov, Aziz B. Yakubov, Yuldash Ibragimov, Bakhtiyar T. Ashurov, Jamshid M. Acta Crystallogr E Crystallogr Commun Research Communications The title polymer, [Cu(SO(4))(CH(5)N(3)O)(2)]( n ), has been synthesized from aqueous solutions of CuSO(4) and semicarbazide. In the crystal structure, the Cu(II) atoms are chelated by two neutral semicarbazide mol­ecules through the oxygen atom and a nitro­gen atom of the amino group. The remaining two positions of the Jahn–Teller-distorted octa­hedral coordination sphere are occupied by oxygen atoms of two sulfate anions in the axial positions. The coordination bonds of the latter associate the polyhedra into polymeric chains running parallel to the c axis. There is a weak intra­molecular hydrogen bond between the N—H group and an oxygen atom of the SO(4) (2–) anion. Thirteen relatively weak inter­molecular hydrogen-bonding inter­actions link the chains into a three-dimensional network. Hirshfeld surface analysis revealed that 64.7% of the inter­molecular inter­actions are from O⋯H/H⋯O contacts and 20.1% from H⋯H contacts. Other inter­actions such as N⋯H/H⋯N or C⋯H/H⋯C contribute less to the crystal packing. International Union of Crystallography 2022-10-20 /pmc/articles/PMC9638975/ /pubmed/36380913 http://dx.doi.org/10.1107/S2056989022010040 Text en © Tadjieva et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Tadjieva, Galiya
Ibragimov, Aziz B.
Yakubov, Yuldash
Ibragimov, Bakhtiyar T.
Ashurov, Jamshid M.
Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′]
title Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′]
title_full Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′]
title_fullStr Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′]
title_full_unstemmed Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′]
title_short Synthesis, crystal structure and Hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) N,O)copper(II)]-μ-sulfato-κ(2) O:O′]
title_sort synthesis, crystal structure and hirshfeld surface analysis of catena-poly[[bis­(semicarbazide-κ(2) n,o)copper(ii)]-μ-sulfato-κ(2) o:o′]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638975/
https://www.ncbi.nlm.nih.gov/pubmed/36380913
http://dx.doi.org/10.1107/S2056989022010040
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