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Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone
The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C(8)H(7)ClO(2), an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H⋯O and weak C—H⋯O hydrogen bonds. A brief compari...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638980/ https://www.ncbi.nlm.nih.gov/pubmed/36380905 http://dx.doi.org/10.1107/S2056989022009835 |
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| author | Priyanka, Prabhakar Jayanna, Bidarur K. Vinaya, Shankara Prasad, Holehundi J. Divakara, Thayamma R. Yathirajan, Hemmige S. Parkin, Sean |
| author_facet | Priyanka, Prabhakar Jayanna, Bidarur K. Vinaya, Shankara Prasad, Holehundi J. Divakara, Thayamma R. Yathirajan, Hemmige S. Parkin, Sean |
| author_sort | Priyanka, Prabhakar |
| collection | PubMed |
| description | The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C(8)H(7)ClO(2), an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H⋯O and weak C—H⋯O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented. |
| format | Online Article Text |
| id | pubmed-9638980 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-96389802022-11-14 Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone Priyanka, Prabhakar Jayanna, Bidarur K. Vinaya, Shankara Prasad, Holehundi J. Divakara, Thayamma R. Yathirajan, Hemmige S. Parkin, Sean Acta Crystallogr E Crystallogr Commun Research Communications The structure of 2-chloro-1-(3-hydroxyphenyl)ethanone, C(8)H(7)ClO(2), an α-haloketone is described. The molecule is planar (r.m.s. deviation = 0.0164 Å) and in the crystal, inversion-symmetric dimers are formed as a result of pairs of strong O—H⋯O and weak C—H⋯O hydrogen bonds. A brief comparison is made with structurally related compounds deposited in the CSD. In addition, the synthesis and some spectroscopic details are presented. International Union of Crystallography 2022-10-20 /pmc/articles/PMC9638980/ /pubmed/36380905 http://dx.doi.org/10.1107/S2056989022009835 Text en © Priyanka et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Priyanka, Prabhakar Jayanna, Bidarur K. Vinaya, Shankara Prasad, Holehundi J. Divakara, Thayamma R. Yathirajan, Hemmige S. Parkin, Sean Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone |
| title | Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone |
| title_full | Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone |
| title_fullStr | Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone |
| title_full_unstemmed | Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone |
| title_short | Synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone |
| title_sort | synthesis and crystal structure of 2-chloro-1-(3-hydroxyphenyl)ethanone |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638980/ https://www.ncbi.nlm.nih.gov/pubmed/36380905 http://dx.doi.org/10.1107/S2056989022009835 |
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