Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols

Ruthenium-catalyzed hydrogen auto-transfer reactions for the direct enantioselective conversion of lower alcohols to higher alcohols are surveyed. These processes enable completely atom-efficient carbonyl addition from alcohol proelectrophiles in the absence of premetalated reagents or metallic redu...

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Detalles Bibliográficos
Autores principales: Ortiz, Eliezer, Shezaf, Jonathan Z., Shen, Weijia, Krische, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9645367/
https://www.ncbi.nlm.nih.gov/pubmed/36516346
http://dx.doi.org/10.1039/d2sc05621f
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author Ortiz, Eliezer
Shezaf, Jonathan Z.
Shen, Weijia
Krische, Michael J.
author_facet Ortiz, Eliezer
Shezaf, Jonathan Z.
Shen, Weijia
Krische, Michael J.
author_sort Ortiz, Eliezer
collection PubMed
description Ruthenium-catalyzed hydrogen auto-transfer reactions for the direct enantioselective conversion of lower alcohols to higher alcohols are surveyed. These processes enable completely atom-efficient carbonyl addition from alcohol proelectrophiles in the absence of premetalated reagents or metallic reductants. Applications in target-oriented synthesis are highlighted, and a brief historical perspective on ruthenium-catalyzed hydrogen transfer processes is given.
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spelling pubmed-96453672022-12-13 Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols Ortiz, Eliezer Shezaf, Jonathan Z. Shen, Weijia Krische, Michael J. Chem Sci Chemistry Ruthenium-catalyzed hydrogen auto-transfer reactions for the direct enantioselective conversion of lower alcohols to higher alcohols are surveyed. These processes enable completely atom-efficient carbonyl addition from alcohol proelectrophiles in the absence of premetalated reagents or metallic reductants. Applications in target-oriented synthesis are highlighted, and a brief historical perspective on ruthenium-catalyzed hydrogen transfer processes is given. The Royal Society of Chemistry 2022-10-26 /pmc/articles/PMC9645367/ /pubmed/36516346 http://dx.doi.org/10.1039/d2sc05621f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Ortiz, Eliezer
Shezaf, Jonathan Z.
Shen, Weijia
Krische, Michael J.
Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols
title Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols
title_full Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols
title_fullStr Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols
title_full_unstemmed Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols
title_short Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols
title_sort historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher alcohols
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9645367/
https://www.ncbi.nlm.nih.gov/pubmed/36516346
http://dx.doi.org/10.1039/d2sc05621f
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