Cargando…
Synthesis of phosphiranes via organoiron-catalyzed phosphinidene transfer to electron-deficient olefins
Herein is reported the structural characterization and scalable preparation of the elusive iron–phosphido complex FpP((t)Bu)(F) (2-F, Fp = (Fe(η(5)-C(5)H(5))(CO)(2))) and its precursor FpP((t)Bu)(Cl) (2-Cl) in 51% and 71% yields, respectively. These phosphide complexes are proposed to be relevant to...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9645374/ https://www.ncbi.nlm.nih.gov/pubmed/36519032 http://dx.doi.org/10.1039/d2sc05011k |