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Modulating the frontier orbitals of L(X)Ga-substituted diphosphenes [L(X)GaP](2) (X = Cl, Br) and their facile oxidation to radical cations

Modulating the electronic structures of main group element compounds is crucial to control their chemical reactivity. Herein we report on the synthesis, frontier orbital modulation, and one-electron oxidation of two L(X)Ga-substituted diphosphenes [L(X)GaP](2) (X = Cl 2a, Br 2b; L = HC[C(Me)N(Ar)](2...

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Detalles Bibliográficos
Autores principales:	Sharma, Mahendra K., Chabbra, Sonia, Wölper, Christoph, Weinert, Hanns M., Reijerse, Edward J., Schnegg, Alexander, Schulz, Stephan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9645402/ https://www.ncbi.nlm.nih.gov/pubmed/36519043 http://dx.doi.org/10.1039/d2sc04207j

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