Alloying Bi-Doped Cs(2)Ag(1–x)Na(x)InCl(6) Nanocrystals with K(+) Cations Modulates Surface Ligands Density and Photoluminescence Efficiency

[Image: see text] We show how, in the synthesis of yellow-emissive Bi-doped Cs(2)Ag(1–x)Na(x)InCl(6) double perovskite nanocrystals (NCs), preventing the transient formation of Ag(0) particles increases the photoluminescence quantum yield (PLQY) of the NCs from ∼30% to ∼60%. Calculations indicate that the presence of even a single Ag(0) species on the surface of a NC introduces deep trap states. The PL efficiency of these NCs is further increased to ∼70% by partial replacement of Na(+) with K(+) ions, up to a 7% K content, due to a lattice expansion that promotes a more favorable ligands packing on the NC surface, hence better surface passivation. A further increase in K(+) lowers the PLQY, due to both the activation of nonradiative quenching channels and a lower oscillator strength of the BiCl(6)→AgCl(6) transition (through which PL emission occurs). The work indicates how a deeper understanding of parameters influencing carrier trapping/relaxation can boost the PLQY of double perovskites NCs.