Surface Properties of Eggshell Powder and Its Influence on Cement Hydration

Using eggshell powder (EP) to replace partial cement in cement-based materials can abate pollution caused by eggshell discard and cement production. In this paper, the surface property of EP and its influence on cement hydration were studied. Quartz powder (QP) and limestone powder (LP) were used as references. First, the chemical composition of EP was characterized. Then, the surface charge properties of these materials were analyzed using zeta potential measurement. The interactions between EP surface and Ca(2+) were discussed based on the zeta potential test. Afterward, a scanning electron microscope (SEM) was applied to observe the morphology of hydrates on the surfaces of these materials. The results indicated that, although the compositions of EP and LP are similar, the surface charge properties are significantly different. This is likely due to the existence of organic matter on the surface of EP and the difference in the atomic structure. As shown from the zeta potential test, EP exhibits similar interaction with Ca(2+) as QP. The interactions between EP surface and Ca(2+) are much weaker than that between LP and Ca(2+). These weak interactions lead to the growth of C–S–H on the surface of EP particles less than that of LP particles. The chemical reactivity of EP can be improved by using heat treatment, electrical oven, etc. This study will provide theoretical support for the better use of EP in cement-based materials.