Cargando…

Transition Metal–(μ-Cl)–Aluminum Bonding in α-Olefin and Diene Chemistry

Olefin and diene transformations, catalyzed by organoaluminum-activated metal complexes, are widely used in synthetic organic chemistry and form the basis of major petrochemical processes. However, the role of M–(μ-Cl)–Al bonding, being proven for certain >C=C< functionalization reactions, rem...

Descripción completa

Detalles Bibliográficos
Autores principales:	Nifant’ev, Ilya E., Salakhov, Ildar I., Ivchenko, Pavel V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9654437/ https://www.ncbi.nlm.nih.gov/pubmed/36363991 http://dx.doi.org/10.3390/molecules27217164

Ejemplares similares

Fair Look at Coordination Oligomerization of Higher α-Olefins
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

DFT Modeling of the Alternating Radical Copolymerization and Alder-Ene Reaction between Maleic Anhydride and Olefins
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

DFT Modeling of Organocatalytic Ring-Opening Polymerization of Cyclic Esters: A Crucial Role of Proton Exchange and Hydrogen Bonding
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Zirconocene-Catalyzed Dimerization of α-Olefins: DFT Modeling of the Zr-Al Binuclear Reaction Mechanism
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Coordination Ring-Opening Polymerization of Cyclic Esters: A Critical Overview of DFT Modeling and Visualization of the Reaction Mechanisms
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Polymer Cold-Flow Improvers for Biodiesel
por: Nifant’ev, Ilya, et al.
Publicado: (2021)

MAO- and Borate-Free Activating Supports for Group 4 Metallocene and Post-Metallocene Catalysts of α-Olefin Polymerization and Oligomerization
por: Nifant’ev, Ilya E., et al.
Publicado: (2023)

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 2—Sidechain Phosphorus-Containing Polyacids
por: Nifant’ev, Ilya E., et al.
Publicado: (2023)

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 1. Polyphosphodiesters
por: Nifant’ev, Ilya E., et al.
Publicado: (2022)

Antibacterial Poly(ε-CL)/Hydroxyapatite Electrospun Fibers Reinforced by Poly(ε-CL)-b-poly(ethylene phosphoric acid)
por: Nifant’ev, Ilya, et al.
Publicado: (2021)

Tandem Synthesis of Ultra-High Molecular Weight Drag Reducing Poly-α-Olefins for Low-Temperature Pipeline Transportation
por: Nifant’ev, Ilya E., et al.
Publicado: (2021)

In Vitro and In Vivo Studies of Biodegradability and Biocompatibility of Poly(εCL)-b-Poly(EtOEP)-Based Films
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Comparative Experimental and Theoretical Study of Mg, Al and Zn Aryloxy Complexes in Copolymerization of Cyclic Esters: The Role of the Metal Coordination in Formation of Random Copolymers
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Mechanistic Insights of BHT-Mg-Catalyzed Ethylene Phosphate’s Coordination Ring-Opening Polymerization: DFT Modeling and Experimental Data
por: Nifant’ev, Ilya, et al.
Publicado: (2018)

Experimental and Theoretical Study of Zirconocene-Catalyzed Oligomerization of 1-Octene
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Raman Spectroscopy Study of Structurally Uniform Hydrogenated Oligomers of α-Olefins
por: Kuznetsov, Sergey M., et al.
Publicado: (2020)

DFT Visualization and Experimental Evidence of BHT-Mg-Catalyzed Copolymerization of Lactides, Lactones and Ethylene Phosphates
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Functionalized Biodegradable Polymers via Termination of Ring-Opening Polymerization by Acyl Chlorides
por: Nifant’ev, Ilya, et al.
Publicado: (2021)

The Use of Branching Agents in the Synthesis of PBAT
por: Nifant’ev, Ilya E., et al.
Publicado: (2022)

Dispersant and Protective Roles of Amphiphilic Poly(ethylene phosphate) Block Copolymers in Polyester/Bone Mineral Composites
por: Nifant’ev, Ilya, et al.
Publicado: (2023)

Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3) O,N,O′)terbium
por: Minyaev, Mikhail E., et al.
Publicado: (2022)

Catalytic Properties of Zirconocene-Based Systems in 1-Hexene Oligomerization and Structure of Metal Hydride Reaction Centers
por: Parfenova, Lyudmila V., et al.
Publicado: (2023)

Phase Equilibria and Interdiffusion in Bimodal High-Density Polyethylene (HDPE) and Linear Low-Density Polyethylene (LLDPE) Based Compositions
por: Salakhov, Ildar I., et al.
Publicado: (2021)

Low-Temperature Mechanical Properties of High-Density and Low-Density Polyethylene and Their Blends
por: Salakhov, Ildar I., et al.
Publicado: (2021)

Data for quantum-chemical modeling of the mechanisms of ring-opening polymerization of methyl ethylene phosphate
por: Nifant'ev, Ilya E., et al.
Publicado: (2019)

Crystal structure of bis(μ(2)-triphenylacetato-κO:κO′)bis(diisobutylaluminium)
por: Vinogradov, Alexander A., et al.
Publicado: (2019)

Osteogenic Differentiation of Human Adipose Tissue-Derived MSCs by Non-Toxic Calcium Poly(ethylene phosphate)s
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Crystal structure of bis(μ(2)-methanolato-κO:κO)hexamethylbis(μ(2)-triphenylacetato-κO:κO′)bis(μ(2)-triphenylacetato-κ(2) O,O′:κO)dialuminiumdilanthanum toluene tetrasolvate
por: Vinogradov, Alexander A., et al.
Publicado: (2018)

A New Approach to Developing Long-Acting Injectable Formulations of Anti-HIV Drugs: Poly(Ethylene Phosphoric Acid) Block Copolymers Increase the Efficiency of Tenofovir against HIV-1 in MT-4 Cells
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Chain-End Functionalization of Poly(ε-caprolactone) for Chemical Binding with Gelatin: Binary Electrospun Scaffolds with Improved Physico-Mechanical Characteristics and Cell Adhesive Properties
por: Nifant’ev, Ilya, et al.
Publicado: (2022)

The structural diversity of heterocycle-fused potassium cyclopentadienides
por: Nifant'ev, Ilya E., et al.
Publicado: (2019)

Bis[μ-bis(2,6-diisopropylphenyl) phosphato-κ(2) O:O′]bis[(2,2′-bipyridine-κ(2) N,N′)lithium] toluene disolvate and its catalytic activity in ring-opening polymerization of ∊-caprolactone and l-dilactide
por: Kalugin, Alexey E., et al.
Publicado: (2019)

Crystal structure and catalytic activity of tetrakis(μ(2)-ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ(2) O:O′)bis(ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ(2) O,O′)dilutetium n-heptane disolvate
por: Minyaev, Mikhail E., et al.
Publicado: (2018)

Polyisobutylenes with Controlled Molecular Weight and Chain-End Structure: Synthesis and Actual Applications
por: Nifant’ev, Ilya E., et al.
Publicado: (2023)

(1R,2S,4r)-1,2,4-Triphenylcyclopentane-1,2-diol and (1R,2S,4r)-4-(2-methoxyphenyl)-1,2-diphenylcyclopentane-1,2-diol: application as initiators for ring-opening polymerization of ∊-caprolactone
por: Komarov, Pavel D., et al.
Publicado: (2019)

Crystal structure of (2,2′-bipyridine-κ(2) N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)
por: Minyaev, Mikhail E., et al.
Publicado: (2018)

[4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium
por: Minyaev, Mikhail E., et al.
Publicado: (2018)

Binding of [Au(dien)Cl]Cl(2) to Tripeptides
por: Best, Sabine L., et al.
Publicado: (1994)

Synthesis, Structure of Nitrogen-Containing Phosphinogold(I) Ferrocenes. In vitro Activity against Bladder and Colon Carcinoma Cell Lines
por: Viotte, Manuella, et al.
Publicado: (1995)

A Predictive Model Towards Site‐Selective Metalations of Functionalized Heterocycles, Arenes, Olefins, and Alkanes using TMPZnCl⋅LiCl
por: Balkenhohl, Moritz, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_nmki0m4u0tqf9ff9karhjpb4v2