Acid Catalyzed Stereocontrolled Ferrier-Type Glycosylation Assisted by Perfluorinated Solvent

Described herein is the first application of perfluorinated solvent in the stereoselective formation of O-/S-glycosidic linkages that occurs via a Ferrier rearrangement of acetylated glycals. In this system, the weak interactions between perfluoro-n-hexane and substrates could augment the reactivity...

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Detalles Bibliográficos
Autores principales: Lu, Zhiqiang, Li, Yanzhi, Xiang, Shaohua, Zuo, Mengke, Sun, Yangxing, Jiang, Xingxing, Jiao, Rongkai, Wang, Yinghong, Fu, Yuqin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9656285/
https://www.ncbi.nlm.nih.gov/pubmed/36364059
http://dx.doi.org/10.3390/molecules27217234

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9656285/
https://www.ncbi.nlm.nih.gov/pubmed/36364059
http://dx.doi.org/10.3390/molecules27217234

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