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Acid Catalyzed Stereocontrolled Ferrier-Type Glycosylation Assisted by Perfluorinated Solvent
Described herein is the first application of perfluorinated solvent in the stereoselective formation of O-/S-glycosidic linkages that occurs via a Ferrier rearrangement of acetylated glycals. In this system, the weak interactions between perfluoro-n-hexane and substrates could augment the reactivity...
Autores principales: | Lu, Zhiqiang, Li, Yanzhi, Xiang, Shaohua, Zuo, Mengke, Sun, Yangxing, Jiang, Xingxing, Jiao, Rongkai, Wang, Yinghong, Fu, Yuqin |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9656285/ https://www.ncbi.nlm.nih.gov/pubmed/36364059 http://dx.doi.org/10.3390/molecules27217234 |
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