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Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer

This paper presents a method for the formation of composite-polymer-containing coatings on MA8 Mg alloy by plasma electrolytic oxidation (PEO), followed by the deposition of a fluoropolymer from an aqueous suspension of superdispersed polytetrafluoroethylene. The Scanning Electron Microscope(SEM), E...

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Autores principales: Mashtalyar, Dmitriy Valerievich, Nadaraia, Konstantine Vakhtangovich, Belov, Evgeny Alekseevich, Imshinetskiy, Igor Mikhaylovich, Sinebrukhov, Sergey Leonidovich, Gnedenkov, Sergey Vasilevich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9656654/
https://www.ncbi.nlm.nih.gov/pubmed/36365659
http://dx.doi.org/10.3390/polym14214667
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author Mashtalyar, Dmitriy Valerievich
Nadaraia, Konstantine Vakhtangovich
Belov, Evgeny Alekseevich
Imshinetskiy, Igor Mikhaylovich
Sinebrukhov, Sergey Leonidovich
Gnedenkov, Sergey Vasilevich
author_facet Mashtalyar, Dmitriy Valerievich
Nadaraia, Konstantine Vakhtangovich
Belov, Evgeny Alekseevich
Imshinetskiy, Igor Mikhaylovich
Sinebrukhov, Sergey Leonidovich
Gnedenkov, Sergey Vasilevich
author_sort Mashtalyar, Dmitriy Valerievich
collection PubMed
description This paper presents a method for the formation of composite-polymer-containing coatings on MA8 Mg alloy by plasma electrolytic oxidation (PEO), followed by the deposition of a fluoropolymer from an aqueous suspension of superdispersed polytetrafluoroethylene. The Scanning Electron Microscope(SEM), Energy Dispersive Spectroscopy(EDS), and X-ray Diffraction(XRD) analyses established morphological features as well as elemental and phase composition of composite coatings. The fact that the pores are filled with a fluoropolymer has been experimentally confirmed. An assessment of the corrosion properties of formed composite coatings revealed a decrease in the corrosion current density by more than four orders of magnitude in comparison with the base PEO layer. The highest resistance to the damaging effects of a corrosive environment, according to the results of long-term exposure tests, was demonstrated by coatings after three treatments with polytetrafluoroethylene. The obtained polymer-containing coatings have antifriction properties, reducing the wear of the coatings by more than 27-fold in comparison with the base PEO layer. It was revealed that composite coatings have superhydrophobic properties: the value of the contact angle reaches 154°, and the hysteresis of the contact angle is less than 10°.
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spelling pubmed-96566542022-11-15 Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer Mashtalyar, Dmitriy Valerievich Nadaraia, Konstantine Vakhtangovich Belov, Evgeny Alekseevich Imshinetskiy, Igor Mikhaylovich Sinebrukhov, Sergey Leonidovich Gnedenkov, Sergey Vasilevich Polymers (Basel) Article This paper presents a method for the formation of composite-polymer-containing coatings on MA8 Mg alloy by plasma electrolytic oxidation (PEO), followed by the deposition of a fluoropolymer from an aqueous suspension of superdispersed polytetrafluoroethylene. The Scanning Electron Microscope(SEM), Energy Dispersive Spectroscopy(EDS), and X-ray Diffraction(XRD) analyses established morphological features as well as elemental and phase composition of composite coatings. The fact that the pores are filled with a fluoropolymer has been experimentally confirmed. An assessment of the corrosion properties of formed composite coatings revealed a decrease in the corrosion current density by more than four orders of magnitude in comparison with the base PEO layer. The highest resistance to the damaging effects of a corrosive environment, according to the results of long-term exposure tests, was demonstrated by coatings after three treatments with polytetrafluoroethylene. The obtained polymer-containing coatings have antifriction properties, reducing the wear of the coatings by more than 27-fold in comparison with the base PEO layer. It was revealed that composite coatings have superhydrophobic properties: the value of the contact angle reaches 154°, and the hysteresis of the contact angle is less than 10°. MDPI 2022-11-01 /pmc/articles/PMC9656654/ /pubmed/36365659 http://dx.doi.org/10.3390/polym14214667 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Mashtalyar, Dmitriy Valerievich
Nadaraia, Konstantine Vakhtangovich
Belov, Evgeny Alekseevich
Imshinetskiy, Igor Mikhaylovich
Sinebrukhov, Sergey Leonidovich
Gnedenkov, Sergey Vasilevich
Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer
title Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer
title_full Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer
title_fullStr Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer
title_full_unstemmed Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer
title_short Features of Composite Layers Created Using an Aqueous Suspension of a Fluoropolymer
title_sort features of composite layers created using an aqueous suspension of a fluoropolymer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9656654/
https://www.ncbi.nlm.nih.gov/pubmed/36365659
http://dx.doi.org/10.3390/polym14214667
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