Cargando…
Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems
The search for new sources of raw materials that can be used in the synthesis of polyurethanes and other polymer groups is extremely important. Currently, according to the principles of green chemistry and a circular economy, waste materials with a high reuse potential are being sought. This article...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9657215/ https://www.ncbi.nlm.nih.gov/pubmed/36363400 http://dx.doi.org/10.3390/ma15217807 |
_version_ | 1784829636185686016 |
---|---|
author | Malewska, Elżbieta Polaczek, Krzysztof Kurańska, Maria |
author_facet | Malewska, Elżbieta Polaczek, Krzysztof Kurańska, Maria |
author_sort | Malewska, Elżbieta |
collection | PubMed |
description | The search for new sources of raw materials that can be used in the synthesis of polyurethanes and other polymer groups is extremely important. Currently, according to the principles of green chemistry and a circular economy, waste materials with a high reuse potential are being sought. This article presents a way of obtaining used-cooking-oil-based compounds capable of participating in the reaction of polyurethane creation. The transesterification reaction can be carried out using a variety of homo- and heterogeneous acid or base catalysts. Here, we looked at the impact of selected catalysts on the course of transesterification reactions, the composition of the post-reaction mixture and the possibility of using the products in polyurethane foam synthesis. The raw materials and the products were analyzed by means of gel permeation chromatography, FTIR spectroscopy and (1)H NMR. The polyurethane foam formation process was analyzed using a FOAMAT(®) apparatus. |
format | Online Article Text |
id | pubmed-9657215 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-96572152022-11-15 Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems Malewska, Elżbieta Polaczek, Krzysztof Kurańska, Maria Materials (Basel) Article The search for new sources of raw materials that can be used in the synthesis of polyurethanes and other polymer groups is extremely important. Currently, according to the principles of green chemistry and a circular economy, waste materials with a high reuse potential are being sought. This article presents a way of obtaining used-cooking-oil-based compounds capable of participating in the reaction of polyurethane creation. The transesterification reaction can be carried out using a variety of homo- and heterogeneous acid or base catalysts. Here, we looked at the impact of selected catalysts on the course of transesterification reactions, the composition of the post-reaction mixture and the possibility of using the products in polyurethane foam synthesis. The raw materials and the products were analyzed by means of gel permeation chromatography, FTIR spectroscopy and (1)H NMR. The polyurethane foam formation process was analyzed using a FOAMAT(®) apparatus. MDPI 2022-11-05 /pmc/articles/PMC9657215/ /pubmed/36363400 http://dx.doi.org/10.3390/ma15217807 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Malewska, Elżbieta Polaczek, Krzysztof Kurańska, Maria Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems |
title | Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems |
title_full | Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems |
title_fullStr | Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems |
title_full_unstemmed | Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems |
title_short | Impact of Various Catalysts on Transesterification of Used Cooking Oil and Foaming Processes of Polyurethane Systems |
title_sort | impact of various catalysts on transesterification of used cooking oil and foaming processes of polyurethane systems |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9657215/ https://www.ncbi.nlm.nih.gov/pubmed/36363400 http://dx.doi.org/10.3390/ma15217807 |
work_keys_str_mv | AT malewskaelzbieta impactofvariouscatalystsontransesterificationofusedcookingoilandfoamingprocessesofpolyurethanesystems AT polaczekkrzysztof impactofvariouscatalystsontransesterificationofusedcookingoilandfoamingprocessesofpolyurethanesystems AT kuranskamaria impactofvariouscatalystsontransesterificationofusedcookingoilandfoamingprocessesofpolyurethanesystems |