The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene

The first examples of [3+2] cycloaddition reactions between 3,3,3-tribromo-1-nitroprop-1-ene (TBMN) were explored on the basis of experimental and theoretical approaches. It was found that reactions involving TBMN and diarylnitrones realized with full regio- and stereoselectivity lead to respective...

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Autores principales: Zawadzińska, Karolina, Gadocha, Zuzanna, Pabian, Kamila, Wróblewska, Aneta, Wielgus, Ewelina, Jasiński, Radomir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9657535/
https://www.ncbi.nlm.nih.gov/pubmed/36363174
http://dx.doi.org/10.3390/ma15217584
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author Zawadzińska, Karolina
Gadocha, Zuzanna
Pabian, Kamila
Wróblewska, Aneta
Wielgus, Ewelina
Jasiński, Radomir
author_facet Zawadzińska, Karolina
Gadocha, Zuzanna
Pabian, Kamila
Wróblewska, Aneta
Wielgus, Ewelina
Jasiński, Radomir
author_sort Zawadzińska, Karolina
collection PubMed
description The first examples of [3+2] cycloaddition reactions between 3,3,3-tribromo-1-nitroprop-1-ene (TBMN) were explored on the basis of experimental and theoretical approaches. It was found that reactions involving TBMN and diarylnitrones realized with full regio- and stereoselectivity lead to respective 3,4-cis-4,5-trans-4-nitroisoxazolidines. The regioselecticity and the molecular mechanism of title processes was analyzed on the basis of the advanced DFT computational study.
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spelling pubmed-96575352022-11-15 The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene Zawadzińska, Karolina Gadocha, Zuzanna Pabian, Kamila Wróblewska, Aneta Wielgus, Ewelina Jasiński, Radomir Materials (Basel) Article The first examples of [3+2] cycloaddition reactions between 3,3,3-tribromo-1-nitroprop-1-ene (TBMN) were explored on the basis of experimental and theoretical approaches. It was found that reactions involving TBMN and diarylnitrones realized with full regio- and stereoselectivity lead to respective 3,4-cis-4,5-trans-4-nitroisoxazolidines. The regioselecticity and the molecular mechanism of title processes was analyzed on the basis of the advanced DFT computational study. MDPI 2022-10-28 /pmc/articles/PMC9657535/ /pubmed/36363174 http://dx.doi.org/10.3390/ma15217584 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zawadzińska, Karolina
Gadocha, Zuzanna
Pabian, Kamila
Wróblewska, Aneta
Wielgus, Ewelina
Jasiński, Radomir
The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene
title The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene
title_full The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene
title_fullStr The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene
title_full_unstemmed The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene
title_short The First Examples of [3+2] Cycloadditions with the Participation of (E)-3,3,3-Tribromo-1-Nitroprop-1-Ene
title_sort first examples of [3+2] cycloadditions with the participation of (e)-3,3,3-tribromo-1-nitroprop-1-ene
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9657535/
https://www.ncbi.nlm.nih.gov/pubmed/36363174
http://dx.doi.org/10.3390/ma15217584
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