New Titanium(IV)-Alkoxide Complexes Bearing Bidentate OO Ligand with the Camphyl Linker as Catalysts for High-Temperature Ethylene Polymerization and Ethylene/1-Octene Copolymerization

In order to increase the thermal stability of olefin polymerization precatalysts, new titanium(IV) complexes with diolate ligands differing in the degree of steric hindrances were synthesized from readily available precursor (±)camphor. The structures of the complexes 1–2 were established by X-ray d...

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Detalles Bibliográficos
Autores principales: Tuskaev, Vladislav A., Gagieva, Svetlana Ch., Kurmaev, Dmitrii A., Nelyubina, Yulia V., Primakov, Petr V., Evseeva, Maria D., Golubev, Evgenii K., Buzin, Mikhail I., Nikiforova, Galina G., Dzhevakov, Pavel B., Privalov, Viktor I., Magomedov, Kasim F., Bulychev, Boris M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9658800/
https://www.ncbi.nlm.nih.gov/pubmed/36365728
http://dx.doi.org/10.3390/polym14214735

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9658800/
https://www.ncbi.nlm.nih.gov/pubmed/36365728
http://dx.doi.org/10.3390/polym14214735

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