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A Computational Study on the Mechanism of Catalytic Cyclopropanation Reaction with Cobalt N-Confused Porphyrin: The Effects of Inner Carbon and Intramolecular Axial Ligand

The factors that affect acceleration and high trans/cis selectivity in the catalytic cyclopropanation reaction of styrene with ethyl diazoacetate by cobalt N-confused porphyrin (NCP) complexes were investigated using density functional theory calculations. The reaction rate was primarily related to...

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Detalles Bibliográficos
Autores principales:	Iwanaga, Osamu, Miyanishi, Mayuko, Tachibana, Toshihiro, Miyazaki, Takaaki, Shiota, Yoshihito, Yoshizawa, Kazunari, Furuta, Hiroyuki
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9658855/ https://www.ncbi.nlm.nih.gov/pubmed/36364093 http://dx.doi.org/10.3390/molecules27217266

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