Cargando…

Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution

The arsenic (As) pollution of water has been eliminated via intensive scientific efforts, with the purpose of giving safe drinking water to millions of people across the world. In this study, the adsorption of As(V) from a synthetic aqueous solution was verified using a Bentonite-Anthracite@Zetag (B...

Descripción completa

Detalles Bibliográficos
Autores principales: El-Aassar, Mohamed R., Alezbaway, Ahmed K., Althobaiti, Ibrahim O., El-Sayed, Mohamed Y., Abu Salem, Hend S., Hassan, Hassan M. A., Alolaimi, Rawan F., El Agammy, Emam F., Mohy-Eldin, Mohamed S., Mohamed, Fathy M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9659286/
https://www.ncbi.nlm.nih.gov/pubmed/36364462
http://dx.doi.org/10.3390/molecules27217635
_version_ 1784830163858489344
author El-Aassar, Mohamed R.
Alezbaway, Ahmed K.
Althobaiti, Ibrahim O.
El-Sayed, Mohamed Y.
Abu Salem, Hend S.
Hassan, Hassan M. A.
Alolaimi, Rawan F.
El Agammy, Emam F.
Mohy-Eldin, Mohamed S.
Mohamed, Fathy M.
author_facet El-Aassar, Mohamed R.
Alezbaway, Ahmed K.
Althobaiti, Ibrahim O.
El-Sayed, Mohamed Y.
Abu Salem, Hend S.
Hassan, Hassan M. A.
Alolaimi, Rawan F.
El Agammy, Emam F.
Mohy-Eldin, Mohamed S.
Mohamed, Fathy M.
author_sort El-Aassar, Mohamed R.
collection PubMed
description The arsenic (As) pollution of water has been eliminated via intensive scientific efforts, with the purpose of giving safe drinking water to millions of people across the world. In this study, the adsorption of As(V) from a synthetic aqueous solution was verified using a Bentonite-Anthracite@Zetag (BT-An@Zetag) composite. The SEM, FT-IR, XRD, DSC, TGA, and SBET techniques were used to characterize the (BT-An@Zetag) composite. The adsorption of As(V) was explored using batch adsorption under varied operating scenarios. Five kinetic modelswere used to investigate kinetic data, whereas three isotherms had been used to fit empirical equilibrium data. According to the findings, the adsorption mechanism of As(V) was best described by the Freundlich isotherm with a maximum monolayer coverage of 38.6 mg/g showing pseudo-second-order mode. The estimated enthalpy (H°) indicates that the adsorption process is both chemical and endothermic.The calculated free energy (G°) indicates that the reaction is nonspontaneous. After four sequential adsorption cycles, the produced BT-An@Zetag composite demonstrated good reusability and a greater adsorption affinity for As(V) ions. Overall, the BT-An@Zetag composite is suited for removing arsenic from wastewater using adsorption as a cost-effective and efficient technique.
format Online
Article
Text
id pubmed-9659286
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-96592862022-11-15 Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution El-Aassar, Mohamed R. Alezbaway, Ahmed K. Althobaiti, Ibrahim O. El-Sayed, Mohamed Y. Abu Salem, Hend S. Hassan, Hassan M. A. Alolaimi, Rawan F. El Agammy, Emam F. Mohy-Eldin, Mohamed S. Mohamed, Fathy M. Molecules Article The arsenic (As) pollution of water has been eliminated via intensive scientific efforts, with the purpose of giving safe drinking water to millions of people across the world. In this study, the adsorption of As(V) from a synthetic aqueous solution was verified using a Bentonite-Anthracite@Zetag (BT-An@Zetag) composite. The SEM, FT-IR, XRD, DSC, TGA, and SBET techniques were used to characterize the (BT-An@Zetag) composite. The adsorption of As(V) was explored using batch adsorption under varied operating scenarios. Five kinetic modelswere used to investigate kinetic data, whereas three isotherms had been used to fit empirical equilibrium data. According to the findings, the adsorption mechanism of As(V) was best described by the Freundlich isotherm with a maximum monolayer coverage of 38.6 mg/g showing pseudo-second-order mode. The estimated enthalpy (H°) indicates that the adsorption process is both chemical and endothermic.The calculated free energy (G°) indicates that the reaction is nonspontaneous. After four sequential adsorption cycles, the produced BT-An@Zetag composite demonstrated good reusability and a greater adsorption affinity for As(V) ions. Overall, the BT-An@Zetag composite is suited for removing arsenic from wastewater using adsorption as a cost-effective and efficient technique. MDPI 2022-11-07 /pmc/articles/PMC9659286/ /pubmed/36364462 http://dx.doi.org/10.3390/molecules27217635 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
El-Aassar, Mohamed R.
Alezbaway, Ahmed K.
Althobaiti, Ibrahim O.
El-Sayed, Mohamed Y.
Abu Salem, Hend S.
Hassan, Hassan M. A.
Alolaimi, Rawan F.
El Agammy, Emam F.
Mohy-Eldin, Mohamed S.
Mohamed, Fathy M.
Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution
title Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution
title_full Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution
title_fullStr Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution
title_full_unstemmed Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution
title_short Fabrication of Novel Bentonite-Anthracite@Zetag (BT-An@Zetag) Composite for the Removal of Arsenic (V) from an Aqueous Solution
title_sort fabrication of novel bentonite-anthracite@zetag (bt-an@zetag) composite for the removal of arsenic (v) from an aqueous solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9659286/
https://www.ncbi.nlm.nih.gov/pubmed/36364462
http://dx.doi.org/10.3390/molecules27217635
work_keys_str_mv AT elaassarmohamedr fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT alezbawayahmedk fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT althobaitiibrahimo fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT elsayedmohamedy fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT abusalemhends fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT hassanhassanma fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT alolaimirawanf fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT elagammyemamf fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT mohyeldinmohameds fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution
AT mohamedfathym fabricationofnovelbentoniteanthracitezetagbtanzetagcompositefortheremovalofarsenicvfromanaqueoussolution