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Metal-free visible-light-induced hydroxy-perfluoroalkylation of conjugated olefins using enamine catalyst

We developed a simple and sustainable method for the hydroxy-perfluoroalkylation of electron-deficient conjugated olefins and styrenes. In this protcol, in situ generated enamine forms electron-donor–accepter (EDA) complexes with perfluoroalkyl iodide, and reaction proceed with visible-light irradia...

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Detalles Bibliográficos
Autores principales: Tagami, Koto, Ofuji, Yu, Kanbara, Tadashi, Yajima, Tomoko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667149/
https://www.ncbi.nlm.nih.gov/pubmed/36425182
http://dx.doi.org/10.1039/d2ra06679c