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Photochemical synthesis of 1,2,4-triazoles via addition reaction of triplet intermediates to diazoalkanes and azomethine ylide intermediates

The reactivity of diazoalkanes most commonly proceeds through the formation of carbene intermediates or dipolar cycloaddition reactions. The reaction of diazoalkanes with intermediates with unpaired electrons, however, is much less elaborated. Herein, we report on the photochemical reaction of accep...

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Detalles Bibliográficos
Autores principales: Cai, Bao-Gui, Bao, Ye-Peng, Pei, Chao, Li, Qian, Li, Lei, Koenigs, Rene M., Xuan, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667952/
https://www.ncbi.nlm.nih.gov/pubmed/36425480
http://dx.doi.org/10.1039/d2sc04720a

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