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Studying the aging of Laponite suspensions using extensional rheology

The effect of aging on the break-up dynamics of Laponite suspensions was studied in an extensional geometry. It was found that samples of increased age undergo stronger necking at the midpoint. The thinning of samples, driven purely by motion of the plates, was compared with standard shear rheology...

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Autores principales: Hayes, M. J., Smith, M. I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Berlin Heidelberg 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9668775/
https://www.ncbi.nlm.nih.gov/pubmed/36383251
http://dx.doi.org/10.1140/epje/s10189-022-00244-9
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author Hayes, M. J.
Smith, M. I.
author_facet Hayes, M. J.
Smith, M. I.
author_sort Hayes, M. J.
collection PubMed
description The effect of aging on the break-up dynamics of Laponite suspensions was studied in an extensional geometry. It was found that samples of increased age undergo stronger necking at the midpoint. The thinning of samples, driven purely by motion of the plates, was compared with standard shear rheology to understand how the dynamics are related to the sample properties. The Laponite suspensions exhibit a growing stress overshoot with monotonically decreasing yield strain as they age. However, it is shown that the thinning curves in extension are only a good indicator of the sample’s static yield stress, being insensitive to its yield strain. These measurements suggest that following an initial linear visco-elastic regime, samples accumulate significant plastic deformations prior to the complete yielding of the sample. The implications of this for the importance of assessing changes to the ductile—brittle nature of samples are also discussed. GRAPHICAL ABSTRACT: [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1140/epje/s10189-022-00244-9
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spelling pubmed-96687752022-11-18 Studying the aging of Laponite suspensions using extensional rheology Hayes, M. J. Smith, M. I. Eur Phys J E Soft Matter Regular Article—Flowing Matter The effect of aging on the break-up dynamics of Laponite suspensions was studied in an extensional geometry. It was found that samples of increased age undergo stronger necking at the midpoint. The thinning of samples, driven purely by motion of the plates, was compared with standard shear rheology to understand how the dynamics are related to the sample properties. The Laponite suspensions exhibit a growing stress overshoot with monotonically decreasing yield strain as they age. However, it is shown that the thinning curves in extension are only a good indicator of the sample’s static yield stress, being insensitive to its yield strain. These measurements suggest that following an initial linear visco-elastic regime, samples accumulate significant plastic deformations prior to the complete yielding of the sample. The implications of this for the importance of assessing changes to the ductile—brittle nature of samples are also discussed. GRAPHICAL ABSTRACT: [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1140/epje/s10189-022-00244-9 Springer Berlin Heidelberg 2022-11-16 2022 /pmc/articles/PMC9668775/ /pubmed/36383251 http://dx.doi.org/10.1140/epje/s10189-022-00244-9 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Regular Article—Flowing Matter
Hayes, M. J.
Smith, M. I.
Studying the aging of Laponite suspensions using extensional rheology
title Studying the aging of Laponite suspensions using extensional rheology
title_full Studying the aging of Laponite suspensions using extensional rheology
title_fullStr Studying the aging of Laponite suspensions using extensional rheology
title_full_unstemmed Studying the aging of Laponite suspensions using extensional rheology
title_short Studying the aging of Laponite suspensions using extensional rheology
title_sort studying the aging of laponite suspensions using extensional rheology
topic Regular Article—Flowing Matter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9668775/
https://www.ncbi.nlm.nih.gov/pubmed/36383251
http://dx.doi.org/10.1140/epje/s10189-022-00244-9
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