Assignment of the Crystal Structure to the Aza-Pinacol Coupling Product by X-ray Diffraction and Density Functional Theory Modeling

[Image: see text] Aza-pinacol coupling of N-benzyl-1-phenylmethanimine using Zn dust affords a mixture of R,S- or R,R-diastereomers in a 1:1 ratio. The R,S-diastereomer is solid with an m.p. of 135 °C, while the R,R-diastereomer is liquid at room temperature. The configuration of stereocenters was d...

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Autores principales: Savateev, Oleksandr, Tarakina, Nadezda V., Tyutyunnik, Alexander P., Rivadeneira, Salvador Martinez, Heske, Julian, Kühne, Thomas D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9670288/
https://www.ncbi.nlm.nih.gov/pubmed/36406529
http://dx.doi.org/10.1021/acsomega.2c05446

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