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Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys

[Image: see text] There is a high demand for eco-friendly, effective, and high-performance corrosion inhibitors for industrial applications. Thus, the corrosion property of aluminum alloys was studied in essential oil-containing sodium chloride solution at various concentrations. Potentiodynamic pol...

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Autores principales: Sanni, Omotayo, Iwarere, Samuel A., Daramola, Michael O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9670707/
https://www.ncbi.nlm.nih.gov/pubmed/36406532
http://dx.doi.org/10.1021/acsomega.2c00540
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author Sanni, Omotayo
Iwarere, Samuel A.
Daramola, Michael O.
author_facet Sanni, Omotayo
Iwarere, Samuel A.
Daramola, Michael O.
author_sort Sanni, Omotayo
collection PubMed
description [Image: see text] There is a high demand for eco-friendly, effective, and high-performance corrosion inhibitors for industrial applications. Thus, the corrosion property of aluminum alloys was studied in essential oil-containing sodium chloride solution at various concentrations. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), surface tests, and weight loss analysis were used to study the corrosion inhibition mechanism of the essential oil. The essential oil showed the highest inhibition efficiency of 97.01% at 1000 ppm. A high efficiency of 96.03% was achieved even after 168 h of exposure. The potentiodynamic polarization test showed that the essential oil is a mixed-type inhibitor. EIS results show better adsorption of the oil on the surface of the aluminum at increased inhibitor concentrations. The Langmuir’s adsorption isotherm model was found to describe the adsorption behavior. The surface morphology of the uninhibited and inhibited specimens examined by a scanning electron microscope equipped with an energy-dispersive X-ray spectroscope confirmed the protective film of the inhibitor molecules on the aluminum surface.
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spelling pubmed-96707072022-11-18 Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys Sanni, Omotayo Iwarere, Samuel A. Daramola, Michael O. ACS Omega [Image: see text] There is a high demand for eco-friendly, effective, and high-performance corrosion inhibitors for industrial applications. Thus, the corrosion property of aluminum alloys was studied in essential oil-containing sodium chloride solution at various concentrations. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), surface tests, and weight loss analysis were used to study the corrosion inhibition mechanism of the essential oil. The essential oil showed the highest inhibition efficiency of 97.01% at 1000 ppm. A high efficiency of 96.03% was achieved even after 168 h of exposure. The potentiodynamic polarization test showed that the essential oil is a mixed-type inhibitor. EIS results show better adsorption of the oil on the surface of the aluminum at increased inhibitor concentrations. The Langmuir’s adsorption isotherm model was found to describe the adsorption behavior. The surface morphology of the uninhibited and inhibited specimens examined by a scanning electron microscope equipped with an energy-dispersive X-ray spectroscope confirmed the protective film of the inhibitor molecules on the aluminum surface. American Chemical Society 2022-11-04 /pmc/articles/PMC9670707/ /pubmed/36406532 http://dx.doi.org/10.1021/acsomega.2c00540 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Sanni, Omotayo
Iwarere, Samuel A.
Daramola, Michael O.
Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys
title Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys
title_full Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys
title_fullStr Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys
title_full_unstemmed Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys
title_short Evaluation of Corrosion Inhibition of Essential Oil-Based Inhibitors on Aluminum Alloys
title_sort evaluation of corrosion inhibition of essential oil-based inhibitors on aluminum alloys
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9670707/
https://www.ncbi.nlm.nih.gov/pubmed/36406532
http://dx.doi.org/10.1021/acsomega.2c00540
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