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Chain Movements at the Topmost Surface of Poly(methyl methacrylate) and Polystyrene Films Directly Evaluated by In Situ High-Temperature Atomic Force Microscopy
[Image: see text] The surfaces of polymeric materials are thermodynamically unstable, and the glass-transition temperature (T(g)) is significantly lower than that in the bulk material. However, the mobility of the chains at the top of the surface has never been directly evaluated. In this study, the...
Autores principales: | Koike, Kouki, Kumaki, Jiro |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9671121/ https://www.ncbi.nlm.nih.gov/pubmed/36318939 http://dx.doi.org/10.1021/acs.langmuir.2c01788 |
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