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Regioselective Ni-Catalyzed reductive alkylsilylation of acrylonitrile with unactivated alkyl bromides and chlorosilanes

Transition-metal catalyzed carbosilylation of alkenes using carbon electrophiles and silylmetal (-B, -Zn) reagents as the nucleophiles offers a powerful strategy for synthesizing organosilicones, by incorporating carbon and silyl groups across on C-C double bonds in one step. However, to the best of...

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Detalles Bibliográficos
Autores principales: Sun, Jinwei, Zhou, Yongze, Gu, Rui, Li, Xin, Liu, Ao, Zhang, Xuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9675790/
https://www.ncbi.nlm.nih.gov/pubmed/36402772
http://dx.doi.org/10.1038/s41467-022-34901-6