Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins

[Image: see text] Herein, we report the first metal-free and molecular halogen reagent-free dihomohalogenation methodology by using Selectfluor as an oxidant and tetrabutylammonium bromide/chloride salts as a halogen source. This effective strategy provides various fluorine-free halogenated products...

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Autores principales: Dağalan, Ziya, Koçak, Ramazan, Daştan, Arif, Nişancı, Bilal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9680025/
https://www.ncbi.nlm.nih.gov/pubmed/36129307
http://dx.doi.org/10.1021/acs.orglett.2c02627
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author Dağalan, Ziya
Koçak, Ramazan
Daştan, Arif
Nişancı, Bilal
author_facet Dağalan, Ziya
Koçak, Ramazan
Daştan, Arif
Nişancı, Bilal
author_sort Dağalan, Ziya
collection PubMed
description [Image: see text] Herein, we report the first metal-free and molecular halogen reagent-free dihomohalogenation methodology by using Selectfluor as an oxidant and tetrabutylammonium bromide/chloride salts as a halogen source. This effective strategy provides various fluorine-free halogenated products easily in quantitative yields from alkenes, alkynes, and natural products.
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spelling pubmed-96800252022-11-23 Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins Dağalan, Ziya Koçak, Ramazan Daştan, Arif Nişancı, Bilal Org Lett [Image: see text] Herein, we report the first metal-free and molecular halogen reagent-free dihomohalogenation methodology by using Selectfluor as an oxidant and tetrabutylammonium bromide/chloride salts as a halogen source. This effective strategy provides various fluorine-free halogenated products easily in quantitative yields from alkenes, alkynes, and natural products. American Chemical Society 2022-09-21 2022-11-18 /pmc/articles/PMC9680025/ /pubmed/36129307 http://dx.doi.org/10.1021/acs.orglett.2c02627 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Dağalan, Ziya
Koçak, Ramazan
Daştan, Arif
Nişancı, Bilal
Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins
title Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins
title_full Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins
title_fullStr Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins
title_full_unstemmed Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins
title_short Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins
title_sort selectfluor and tbax (cl, br) mediated oxidative chlorination and bromination of olefins
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9680025/
https://www.ncbi.nlm.nih.gov/pubmed/36129307
http://dx.doi.org/10.1021/acs.orglett.2c02627
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