B(C(6)F(5))(3)-catalyzed oxidation of α-diazoesters using DMF and molecular oxygen as oxygen sources

A metal-free catalytic oxidation of α-diazoesters via a green environmental-friendly route was developed. The α-diazoesters were converted to α-ketoesters using DMF and molecular oxygen as oxygen sources and B(C(6)F(5))(3) as the catalyst, without any additives. This protocol has a broad adaptabilit...

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Detalles Bibliográficos
Autores principales: Wang, Bei, Zhang, Guo-Min, Zhang, Hua, Wang, Ji-Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682326/
https://www.ncbi.nlm.nih.gov/pubmed/36505720
http://dx.doi.org/10.1039/d2ra05739e
Descripción
Sumario:A metal-free catalytic oxidation of α-diazoesters via a green environmental-friendly route was developed. The α-diazoesters were converted to α-ketoesters using DMF and molecular oxygen as oxygen sources and B(C(6)F(5))(3) as the catalyst, without any additives. This protocol has a broad adaptability of substrates and good compatibility with a range of functional groups, and it offers new insight into reactions catalyzed by B(C(6)F(5))(3).

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