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Towards new coordination modes of 1,2,3-triazolylidene: controlled by the nature of the 1(st) metalation in a heteroditopic bis-NHC ligand

An unusual effect of the nature of the first metal coordination of a heteroditopic N-heterocyclic carbene ligand (L2) towards the coordination behavior of 1,2,3-tzNHC is explored. The first metal coordination at the ImNHC site (complexes 3 and 4) was noted to substantially influence the electronics...

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Detalles Bibliográficos
Autores principales:	Illam, Praseetha Mathoor, Tiwari, Chandra Shekhar, Rit, Arnab
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682892/ https://www.ncbi.nlm.nih.gov/pubmed/36507188 http://dx.doi.org/10.1039/d2sc05024b

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