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Ni(12) tetracubane cores with slow relaxation of magnetization and efficient charge utilization for photocatalytic hydrogen evolution

We report two Ni(12) multicubane topologies enclosed in the polyanions [Ni(12)(OH)(9)(WO(4))(3)(PO(4))(B-α-PW(9)O(34))(3)](21−){Ni(12)W(30)} and [Ni(12)(OH)(9)(HPO(4))(3)(PO(4))(B-α-PW(9)O(34))(A-α-PW(9)O(34))(2)](21−){Ni(12)W(27)} that magnetically behave as Ni(12) units clearly distinguishing them...

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Detalles Bibliográficos
Autores principales:	Tanuhadi, Elias, Cano, Joan, Batool, Samar, Cherevan, Alexey, Eder, Dominik, Rompel, Annette
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9686624/ https://www.ncbi.nlm.nih.gov/pubmed/36561542 http://dx.doi.org/10.1039/d2tc03508a

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