Cargando…

SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor

In this present work, we demonstrate an efficient electrochemical sensor for the detection of hydrogen peroxide (H(2)O(2)) using a glassy carbon electrode (GCE) modified with a ternary nanocomposite of tin oxide QDs/GO/PPy (SGP2). An in situ chemical oxidative polymerization method was used to creat...

Descripción completa

Detalles Bibliográficos
Autores principales: Molahalli, Vandana, Sharma, Aman, Shetty, Apoorva, Hegde, Gurumurthy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9688144/
https://www.ncbi.nlm.nih.gov/pubmed/36354492
http://dx.doi.org/10.3390/bios12110983
_version_ 1784836193135886336
author Molahalli, Vandana
Sharma, Aman
Shetty, Apoorva
Hegde, Gurumurthy
author_facet Molahalli, Vandana
Sharma, Aman
Shetty, Apoorva
Hegde, Gurumurthy
author_sort Molahalli, Vandana
collection PubMed
description In this present work, we demonstrate an efficient electrochemical sensor for the detection of hydrogen peroxide (H(2)O(2)) using a glassy carbon electrode (GCE) modified with a ternary nanocomposite of tin oxide QDs/GO/PPy (SGP2). An in situ chemical oxidative polymerization method was used to create the SGP2 nanocomposite. FTIR, XRD, HR TEM, CV, DPV, and impedance analysis were used to characterize the nanocomposite. The SGP2 nanocomposite modified GCE can be used to create an effective H(2)O(2) electrochemical sensor with high sensitivity and a low detection limit (LOD). With SGP2 modified GCE, the electrochemical detection test for H(2)O(2) was carried out using cyclic voltammetry (CV) and amperometric methods. The SGP2 modified GCE shows improved sensing capabilities, resulting in considerable sensitivity of 11.69 µA mM cm(−2) and a very low limit of detection (LOD) of 0.758 µM for a broad linear range of H(2)O(2) concentration from 0.1 mM to 0.8 mM with a correlation coefficient R(2) = 0.9886. Additionally, the performance of the SGP2-modified GCE electrode is on par with or nonetheless superior to that of the other functional materials that have been reported for H(2)O(2). As a result, our findings suggest that combining conductive polymer with metal oxide may be a useful method for producing sophisticated and affordable electrochemical sensors.
format Online
Article
Text
id pubmed-9688144
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-96881442022-11-25 SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor Molahalli, Vandana Sharma, Aman Shetty, Apoorva Hegde, Gurumurthy Biosensors (Basel) Article In this present work, we demonstrate an efficient electrochemical sensor for the detection of hydrogen peroxide (H(2)O(2)) using a glassy carbon electrode (GCE) modified with a ternary nanocomposite of tin oxide QDs/GO/PPy (SGP2). An in situ chemical oxidative polymerization method was used to create the SGP2 nanocomposite. FTIR, XRD, HR TEM, CV, DPV, and impedance analysis were used to characterize the nanocomposite. The SGP2 nanocomposite modified GCE can be used to create an effective H(2)O(2) electrochemical sensor with high sensitivity and a low detection limit (LOD). With SGP2 modified GCE, the electrochemical detection test for H(2)O(2) was carried out using cyclic voltammetry (CV) and amperometric methods. The SGP2 modified GCE shows improved sensing capabilities, resulting in considerable sensitivity of 11.69 µA mM cm(−2) and a very low limit of detection (LOD) of 0.758 µM for a broad linear range of H(2)O(2) concentration from 0.1 mM to 0.8 mM with a correlation coefficient R(2) = 0.9886. Additionally, the performance of the SGP2-modified GCE electrode is on par with or nonetheless superior to that of the other functional materials that have been reported for H(2)O(2). As a result, our findings suggest that combining conductive polymer with metal oxide may be a useful method for producing sophisticated and affordable electrochemical sensors. MDPI 2022-11-07 /pmc/articles/PMC9688144/ /pubmed/36354492 http://dx.doi.org/10.3390/bios12110983 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Molahalli, Vandana
Sharma, Aman
Shetty, Apoorva
Hegde, Gurumurthy
SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor
title SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor
title_full SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor
title_fullStr SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor
title_full_unstemmed SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor
title_short SnO(2)QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor
title_sort sno(2)qds deposited on go/ppy-modified glassy carbon electrode for efficient electrochemical hydrogen peroxide sensor
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9688144/
https://www.ncbi.nlm.nih.gov/pubmed/36354492
http://dx.doi.org/10.3390/bios12110983
work_keys_str_mv AT molahallivandana sno2qdsdepositedongoppymodifiedglassycarbonelectrodeforefficientelectrochemicalhydrogenperoxidesensor
AT sharmaaman sno2qdsdepositedongoppymodifiedglassycarbonelectrodeforefficientelectrochemicalhydrogenperoxidesensor
AT shettyapoorva sno2qdsdepositedongoppymodifiedglassycarbonelectrodeforefficientelectrochemicalhydrogenperoxidesensor
AT hegdegurumurthy sno2qdsdepositedongoppymodifiedglassycarbonelectrodeforefficientelectrochemicalhydrogenperoxidesensor