Direct Observation of Evolution from Amorphous Phase to Strain Glass

The amorphous phase and strain glass are both disordered states of solids. The amorphous phase is an atomic packing disordered phase, while strain glass is a glassy state with transformation strain disorder in a crystalline matrix, which both bring extraordinary properties to alloys. Previous studies have mostly focused on the properties and structure of single glass; however, the link between them has seldom been considered. In this work, the specimen of the almost amorphous state was obtained from the heavy-defects-doping Fe(67.8)Pd(32.2) strain glass ingot by arc melting and 90% cold rolling, which were characterized by amorphous packages in X-ray diffraction and amorphous rings in transmission electron microscope diffraction. The evolution from the amorphous phase (metallic glass) back to strain glass was directly observed by an in situ high-resolution transmission electron microscope, which revealed that strain nanodomains began to form on the amorphous matrix below the crystallization temperature of the amorphous phase. Here, direct observation of the evolution process provides a theoretical basis for achieving precise control of crystallinity to obtain the desired microstructure, while the study of the unusual crystallization process offers a possible way to tailor the mechanical and functional properties through tuning the amorphous and strain glass coexistence. This work presents the specific pathway and realization possibilities for the design of glass composite materials with enhanced properties.