Cargando…

Synthesis of Biobased Hydroxyl-Terminated Oligomers by Metathesis Degradation of Industrial Rubbers SBS and PB: Tailor-Made Unsaturated Diols and Polyols

Biobased hydroxyl-terminated polybutadiene (HTPB) was successfully synthesized in a one-pot reaction via metathesis degradation of industrial rubbers. Thus, polybutadiene (PB) and poly(styrene-butadiene-styrene) (SBS) were degraded via metathesis with high yields (>94%), using the fatty alcohol 1...

Descripción completa

Detalles Bibliográficos
Autores principales:	Burelo, Manuel, Gutiérrez, Selena, Treviño-Quintanilla, Cecilia D., Cruz-Morales, Jorge A., Martínez, Araceli, López-Morales, Salvador
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9692933/ https://www.ncbi.nlm.nih.gov/pubmed/36433100 http://dx.doi.org/10.3390/polym14224973

Ejemplares similares

Metathesis Transformations of Natural Products: Cross-Metathesis of Natural Rubber and Mandarin Oil by Ru-Alkylidene Catalysts
por: Martínez, Araceli, et al.
Publicado: (2012)

Overcoming the low reactivity of biobased, secondary diols in polyester synthesis
por: Weinland, Daniel H., et al.
Publicado: (2022)

Three-Component Stereoselective Enzymatic Synthesis of Amino-Diols and Amino-Polyols
por: Ford, Grayson J., et al.
Publicado: (2022)

A Cp(tt)‐Based Trioxo‐Rhenium Catalyst for the Deoxydehydration of Diols and Polyols
por: Li, Jing, et al.
Publicado: (2018)

Sophorolipid-Based Oligomers as Polyol Components for Polyurethane Systems
por: Sonnabend, Maresa, et al.
Publicado: (2021)

Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks
por: Abderrezak, Meriem K, et al.
Publicado: (2015)

Exploring the Effect of Poly(propylene carbonate) Polyol in a Biobased Epoxy Interpenetrating Network
por: Roudsari, Ghodsieh Mashouf, et al.
Publicado: (2017)

Unsaturated Copolyesters from Macrolactone/Norbornene: Toward Reaction Kinetics of Metathesis Copolymerization Using Ruthenium Carbene Catalysts
por: Martínez, Araceli, et al.
Publicado: (2022)

Synthesis of Jatropha-Oil-Based Polyester Polyol as Sustainable Biobased Material for Waterborne Polyurethane Dispersion
por: Sundang, Murni, et al.
Publicado: (2022)

Synthetic Polyisoprene Rubber as a Mimic of Natural Rubber: Recent Advances on Synthesis, Nanocomposites, and Applications †
por: Cruz-Morales, Jorge A., et al.
Publicado: (2023)

Investigation of the High-Temperature and Rheological Properties for Asphalt Sealant Modified by SBS and Rubber Crumb
por: Gong, Yafeng, et al.
Publicado: (2022)

High-Performance Biobased Unsaturated Polyester Nanocomposites with Very Low Loadings of Graphene †
por: Liu, Chengguo, et al.
Publicado: (2018)

Effect of the Addition of Biobased Polyols on the Thermal Stability and Flame Retardancy of Polyurethane and Poly(urea)urethane Elastomers
por: Mizera, Kamila, et al.
Publicado: (2021)

Preparation of Functionalized α,β-Unsaturated Sulfonamides via Olefin Cross-Metathesis
por: Woźniak, Łukasz, et al.
Publicado: (2020)

Ferrocene-Containing Conjugated Oligomers Synthesized by Acyclic Diene Metathesis Polymerization
por: Gao, Xin, et al.
Publicado: (2019)

Synthesis of Biobased Long-Chain Polyesters by Acyclic Diene Metathesis Polymerization and Tandem Hydrogenation and Depolymerization with Ethylene
por: Nomura, Kotohiro, et al.
Publicado: (2020)

Synthesis of High-Molecular-Weight Biobased Aliphatic Polyesters by Acyclic Diene Metathesis Polymerization in Ionic Liquids
por: Wang, Xiuxiu, et al.
Publicado: (2023)

Efficient Conversion of Renewable Unsaturated Fatty Acid Methyl Esters by Cross-Metathesis with Eugenol
por: Le, Duy, et al.
Publicado: (2018)

Application of high-strength biodegradable polyurethanes containing different ratios of biobased isomannide and poly (ϵ-caprolactone) diol
por: Lim, Dong-In, et al.
Publicado: (2013)

Effect of Carbon Black Nanofiller on Adhesion Properties of SBS Rubber Surfaces Treated by Low-Pressure Plasma
por: Tyczkowski, Jacek, et al.
Publicado: (2020)

Influence of Curing Agent Amount on Properties of Dynamic Vulcanized Phenyl Silicone Rubber-SEBS-SBS System
por: Zhao, Chunxu, et al.
Publicado: (2022)

Synthesis, Characterization and Application of Biobased Unsaturated Polyester Resin Reinforced with Unmodified/Modified Biosilica Nanoparticles
por: Embirsh, Hifa Salah Adeen, et al.
Publicado: (2023)

Grubbs Cross-Metathesis Pathway for a Scalable Synthesis of γ-Keto-α,β-unsaturated Esters
por: Nair, Reji N., et al.
Publicado: (2014)

Spectroscopic and Rheological Cross-Analysis of Polyester Polyol Cure Behavior: Role of Polyester Secondary Hydroxyl Content
por: Tilly, Joseph C., et al.
Publicado: (2019)

Production of hydrophobic amino acids from biobased resources: wheat gluten and rubber seed proteins
por: Widyarani, et al.
Publicado: (2016)

Effect of Compatibilization on Biobased Rubber-Toughened Poly(trimethylene terephthalate): Miscibility, Morphology, and Mechanical Properties
por: Snowdon, Michael R., et al.
Publicado: (2018)

Preparation of Octadecyl Amine Grafted over Waste Rubber Powder (ODA-WRP) and Properties of Its Incorporation in SBS-Modified Asphalt
por: Han, Meizhao, et al.
Publicado: (2019)

Performance-Guided Design of Permeable Asphalt Concrete with Modified Asphalt Binder Using Crumb Rubber and SBS Modifier for Sponge Cities
por: Huang, Wentong, et al.
Publicado: (2021)

Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt
por: Zhao, Zhizhong, et al.
Publicado: (2022)

New manager for CERN's SBS branch
Publicado: (1998)

Design of Dithiobenzoate RAFT Agent Bearing Hydroxyl Groups and Its Application in RAFT Polymerization for Telechelic Diol Polymers
por: Kinoshita, Keita, et al.
Publicado: (2017)

Synthesis and characterization of hydroxyl-terminated butadiene-end-capped polyisobutylene and its use as a diol for polyurethane preparation
por: Wu, Kangda, et al.
Publicado: (2020)

Mechanical Performance of Warm-Mixed Porous Asphalt Mixture with Steel Slag and Crumb-Rubber–SBS Modified Bitumen for Seasonal Frozen Regions
por: Cheng, Yongchun, et al.
Publicado: (2019)

Rapid Screening of Polyol Polyketides from Marine Dinoflagellates
por: Morales-Amador, Adrián, et al.
Publicado: (2022)

Lactones 41.† Synthesis and Microbial Hydroxylation of Unsaturated Terpenoid Lactones with p-Menthane Ring Systems
por: Grudniewska, Aleksandra, et al.
Publicado: (2013)

One‐step Synthesis of End‐Functionalized Hydrogenated Nitrile‐Butadiene Rubber by Combining the Functional Metathesis with Hydrogenation
por: Liu, Juan, et al.
Publicado: (2020)

Voltammetric Response of Alizarin Red S-Confined Film-Coated Electrodes to Diol and Polyol Compounds: Use of Phenylboronic Acid-Modified Poly(ethyleneimine) as Film Component
por: Takahashi, Shigehiro, et al.
Publicado: (2018)

Upgrading Sustainable Polyurethane Foam Based on Greener Polyols: Succinic-Based Polyol and Mannich-Based Polyol
por: de Luca Bossa, Ferdinando, et al.
Publicado: (2020)

Fully Bio-Based Thermosetting Polyurethanes from Bio-Based Polyols and Isocyanates
por: Morales-Cerrada, Roberto, et al.
Publicado: (2021)

Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization
por: Suriboot, Jakkrit, et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_lvmoour7m7r7g145h3huf23nk1